Donor-Acceptor Complexes of Linear Oligopyrroles with Boron Trifluoride. Spectral Studies and Quantum-Chemical Simulation

摘要

Intermediate products of synthesis of the boron trifluoride complexes with linear oligopyrroles are found. By means of electronic spectroscopy it was shown that the reaction of linear oligopyrroles with boron trifluoride in solutions resulted in the formation of stable donor-acceptor complexes. Their composition was established and the formation constants were evaluated. It was shown that transformation of these complexes in the corresponding borofluoride complexes is possible only while boiling the reaction mixture. By means of quantum-chemical methods the structural and energy parameters of the donor-acceptor complexes under study were calculated.