Preparation of Non-Valence Compounds of Zinc(II) with 1,2- and 1,4-Benzenedicarboxylic Acids via Self-Assembly

摘要

Nanostructured non-valence compounds based on coordination compounds of zinc(II) with phthalic and terephthalic acids have been prepared. The purity and composition of prepared compounds have been elucidated from X-ray diffraction analysis, IR spectroscopy, elemental analysis, and therrnogravimetry studies; thermal decomposition of the non-valence compounds has been studied as well. The prepared self-assembled compounds are co-precipitated with one water molecule and 1.5 acetic acid molecules per unit of the dicarboxylic acid: [Zn4(OH)6·o-C6H4(COO)2]H2O-1.5CH3COOH and [Zn4(OH)6·p-C6(COO)2·H2O 1.5CH3COOH.