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Grafting acrylic acid onto polypropylene by reactive extrusion with pre-irradiated PP as initiator

机译:以预辐照聚丙烯为引发剂,通过反应挤出将丙烯酸接枝到聚丙烯上

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摘要

In this paper,the modification of polypropylene(PP)with acrylic acid(AA)by reactive extrusion using pre-irradiated PP(rPP)as initiator was investigated.It was found the relatively high graft degree(Gd)and slight degradation of modified PP was obtained when 20 wt% rPP was used.This result can be explained in terms of effective concentration of free radicals.Compared with the neat PP,the modified PP showed the high-notched impact strength and improved adhesion of PP to polar substrate.This technique is of potential industrial interest for PP modification.
机译:本文研究了以预辐照PP(rPP)为引发剂通过反应挤出对丙烯酸(AA)进行丙烯酸改性的聚丙烯(PP),发现接枝度(Gd)较高,降解程度较小。当使用20 wt%的rPP时,可得到自由基。这一结果可以用自由基的有效浓度来解释。与纯PP相比,改性PP显示出高缺口冲击强度并提高了PP与极性基材的附着力。该技术在PP改性方面具有潜在的工业价值。

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