Noble Metal Promoted CeO2-ZrO2-Supported Ni Catalysts for Liquid-Phase Hydrogenation of Cinnamaldehyde

摘要

Pd or Pt promoted CeO2-ZrO2-supported Ni catalysts exhibited superior catalytic activity to the hitherto known Ni catalysts for liquid-phase hydrogenation of cinnamaldehyde at moderate conditions. Under similar experimental conditions, the unpromoted catalyst was selective for hydrocinnamaldehyde product (C=C hydrogenation) whereas the promoted catalyst yielded 3-phenyl propanol (C=C and C=0 hydrogenation product). Enhanced dispersion of Ni was the cause for higher activity of the promoted Ni catalysts.