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Nitrogen-doped anatase titania nanorods with reactive {101} + {010} facets exposure produced from ultrathin titania nanosheets for high photocatalytic performance

机译:由超薄二氧化钛纳米片生产的具有反应性{101} + {010}面的氮掺杂锐钛矿二氧化钛纳米棒,可实现高光催化性能

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摘要

To obtain high performance catalysts for the photooxidation of organic pollutants in water, nitrogen-doped TiO2 nanorods with {101} + {010} facets exposure were successfully synthesized by using ultrathin two-dimensional titania nanosheets as precursor. The nitrogen-doped one-dimensional nanorods had a uniform size within 100 nm. The crystal structure of nitrogen-doped TiO2 nanorods (anatase) didn't alter even though subjected from morphology transformation, however, their crystallinity improved tremendously, and the exposure and proportion of active facets changed, which synergistically boosted the catalytic efficiency. This integrated technology including modification, morphology and phase control might be indicative for fabrication of advanced photocatalysts to remedy environmental pollutant and produce clean energy in the future. (C) 2016 Elsevier B.V. All rights reserved.
机译:为了获得用于水中有机污染物光氧化的高性能催化剂,以超薄二维二氧化钛纳米片为前驱体,成功合成了具有{101} + {010}面的氮掺杂TiO2纳米棒。氮掺杂的一维纳米棒的尺寸在100 nm以内。氮掺杂的TiO2纳米棒(锐钛矿)即使经过形态转变也没有改变,但其结晶度有了很大的提高,活性面的暴露和比例也发生了变化,从而协同提高了催化效率。包括修饰,形态和相控制在内的这项集成技术可能预示着先进光催化剂的制造,以在将来补救环境污染物并产生清洁能源。 (C)2016 Elsevier B.V.保留所有权利。

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