Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

摘要

A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (~1H, ~(13)C, and ~(31)P) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.