Relation Between the Microstructure and Properties of Commercial Titanium Alloys and the Parameters of Gas Nitriding

摘要

Titanium alloys are unique materials with an excellent combination of properties. However, their applications are limited due to low surface hardness. In the present work gas nitriding is performed with the aim of improving the surface properties of commercial titanium alloys. Four widely used titanium alloys, namely. Ti - 6 percent Al -4 percent V. Ti - 6 percent Al - 2 percent Sn - 4 percent Zr - 2 percent Mo. Ti - 8 percent Al - 1 percent Mo - 1 percent V. and Ti - 10 percent V - 3 percent Fe - 3 percent Al. are studied. The process is performed in a nitrogen atmosphere at 950 and 1050 deg C for 1,3. and 5 h. The resulting surface hardness exceeds the normal value for titanium alloys by a factor of 3 - 5 due to the change in the phase composition of the surface layer, yielding a solid solution of nitrogen in an a-Ti phase, a TiN nitride, and TiO_2 dioxide. The influence of the parameters of the treatment process and the chemical composition of the alloys on the phase composition, microstructure. microhardness. and thickness of the surface layer is analyzed. It is shown that nitriding of alloys with a- and (a - P)-structures al 1050 deg C yields surface layers with in homogeneous composition and irregular thickness, whereas after nitriding at 950 deg C the surface layers are homogeneous and have high properties. Practical recommendations are given for choosing nitriding parameters for different alloys and variants of application are discussed.