Multicomponent reactions of dimethyl methoxymalonate and dialkyl acetylenedicarboxylate in the presence of N-Nucleophiles: One-pot synthesis of 2H-pyridinyl-2-butenedioates in water

Khalilzadeh M.A.; Hossaini Z.; Kharian S.

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Multicomponent reactions of dimethyl methoxymalonate and dialkyl acetylenedicarboxylate in the presence of N-Nucleophiles: One-pot synthesis of 2H-pyridinyl-2-butenedioates in water

机译：N-亲核试剂存在下甲氧基丙二酸二甲酯与乙酰二羧酸二烷基酯的多组分反应：水中一锅合成2H-吡啶基-2-丁烯二酸酯

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摘要

An efficient synthesis of 2H-pyridinyl-2-butenedioate derivatives via reaction of dimethyl methoxymalonate and dialkyl acetylenedicarboxylate in the presence of N-nucleophiles in water as a solvent is described.

机译：描述了通过N-亲核试剂在水中作为溶剂，通过甲氧基丙二酸二甲酯和乙酰二羧酸二烷基酯的反应，有效合成2H-吡啶基-2-丁烯二酸酯衍生物。

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《Molecular diversity》 |2010年第3期|共5页
作者
Khalilzadeh M.A.; Hossaini Z.; Kharian S.;
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正文语种 eng
中图分类分子物理学、原子物理学;
关键词
Acetylenic ester; Dimethyl methoxymalonate; N-heterocycles; Three-component reaction;

机译：乙炔酯;甲氧基丙二酸二甲酯;N-杂环;三组分反应;

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1. Multicomponent reactions of dimethyl methoxymalonate and dialkyl acetylenedicarboxylate in the presence of N-Nucleophiles: One-pot synthesis of 2H-pyridinyl-2-butenedioates in water [J] . Khalilzadeh M.A., Hossaini Z., Kharian S. Molecular diversity . 2010,第3期

机译：N-亲核试剂存在下甲氧基丙二酸二甲酯与乙酰二羧酸二烷基酯的多组分反应：水中一锅合成2H-吡啶基-2-丁烯二酸酯
2. Efficient Synthesis of Tetrahydropyrimidines and Pyrrolidines by a Multicomponent Reaction of Dialkyl Acetylenedicarboxylates (=Dialkyl But-2-ynedioates), Amines, and Formaldehyde in the Presence of Iodine as a Catalyst† [J] . Biswanath Das, Boddu Shashi Kanth, Digambar Balaji Shinde, Helvetica Chimica Acta . 2011,第11期

机译：在碘作为催化剂的情况下，通过乙二羧酸二烷基酯（=丁-2-炔基二烷基酯），胺和甲醛的多组分反应，高效合成四氢嘧啶和吡咯烷†
3. Efficient synthesis of tetrahydropyrimidines and pyrrolidines by a multicomponent reaction of dialkyl acetylenedicarboxylates (=dialkyl but-2-ynedioates), amines, and formaldehyde in the presence of iodine as a catalyst [J] . Das B., Kanth B.S., Shinde D.B., Helvetica chimica acta . 2011,第11期

机译：在碘作为催化剂的情况下，通过乙炔二羧酸二烷基酯（=丁-2-炔基二烷基酯），胺和甲醛的多组分反应，高效合成四氢嘧啶和吡咯烷
4. Synthesis of novel β-aminophosphonates by diastereoselective three-component reaction between triphenylphosphite and dialkyl acetylenedicarboxylates in the presence of 2-aminobenzonitril [C] . Nader Zabarjad-Shiraz, Behzad Mohammadi European Symposium on Organic Chemistry . 2009

机译：在2-氨基硝基亚硝基存在下，三苯基磷酸酯和二烷基二羧酸甲酸二烷基二烷基二组分反应对新的β-氨基膦酸盐的合成
5. Exploring Enantioselective and Multicomponent One-Pot Reactions Utilizing Alkynes as Linchpins Toward Biologically Active Molecules [D] . Horton, Jade A. 2018

机译：利用alkynes作为朝向生物活性分子的临床选择性和多组分单盆反应探索酶促和多组分反应
6. Regioselectivity and diastereoselectivity of three-component reaction of α-amino acid dialkyl acetylenedicarboxylates and 2-arylidene-13-indanediones [O] . Liang Chen, Jing Sun, Ying Huang, -1

机译：α-氨基酸乙炔二羧酸二烷基酯和2-亚芳基-13-茚二酮的三组分反应的区域选择性和非对映选择性
7. One-pot, three component reactions between isocyanides and dialkyl acetylenedicarboxylates in the presence of phenyl isocyanate: synthesis of dialkyl 2-(alkyl/arylimino)-2,5-dihydro-5-oxo-1-phenyl-1H-pyrrole-3,4-dicarboxylate [O] . Khatereh Khandan-Barani, Malek T. Maghsoodlou, Nourallah Hazeri, 2011

机译：在异氰酸苯酯存在下异氰化物与乙炔二羧酸二烷基酯之间的一锅三组分反应：2-（烷基/芳基亚氨基）-2,5-二氢-5-氧代-1-苯基-1H-吡咯-3-二烷基酯的合成， 4二羧酸酯
8. High-Pressure Hydrogenation of Carbon Monoxide to Isoparaffinic Hydrocarbons (Isosynthesis). Part II. Experiments on Multicomponent Catalysts and Reactions of Dimethyl Ether [R] . Pichler, H., Ziesecke, K. H. 1949

机译：一氧化碳高压加氢成异链烷烃（异构化合成）。第二部分。多组分催化剂及二甲醚反应实验

Multicomponent reactions of dimethyl methoxymalonate and dialkyl acetylenedicarboxylate in the presence of N-Nucleophiles: One-pot synthesis of 2H-pyridinyl-2-butenedioates in water

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