Metallosiloxanes containing period 5 transition metals: synthesis and X-ray studies of three cadmium siloxanes

摘要

Hydrolysis of PhSi(OEt)(3) in the presence of MOH (M = K, Na) and CdBr2 affords new cadmium siloxanes of sandwich type, whose encapsulated species (Br-, H2O, OH) are defined by the solvent used for synthesis and crystallization.