Synthesis and X-ray Structural Studies Of Novel Metal-Organic Complex: Diiodobis(2-aminopyridine)Cadmium(II) Single Crystal

摘要

A new metal-organic hybrid complex, [Cd(ap)_2I_2] (DIAC), (ap = 2-aminopyridine) was synthesized and characterized by single crystal X-ray diffraction, High resolution X-ray diffraction(HRXRD) and UV-Vis-NIR transmission. The DIAC crystallize in monoclinic crystal system, space group P2_1/n. The coordination geometry around the Cd(II) centre is a distorted tetrahedral. The high resolution X-ray diffraction studies (HRXRD) reveals that the crystalline perfection of as grown single crystal is fairly good.