Kinetics of chlorination and carbochlorination of pure tantalum and niobium pentoxides

E. Allain

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Kinetics of chlorination and carbochlorination of pure tantalum and niobium pentoxides

机译：纯钽和五氧化二铌的氯化和碳氯化反应动力学

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摘要

Kinetics of chlorination and carbochlorination of pureNb2O5 and Ta2O5 were studied by thermogravimetric analysisbetween 385℃ and 1000℃using Cl2-N2 and Cl2-CO-N2 gasmixtures. Standard free energy changes of the reactions and phasestability diagrams of Nb-O-Cl and Ta-O-Cl systems were calculated.

机译：采用Cl2-N2和Cl2-CO-N2混合气，通过热重分析在385℃和1000℃之间对纯Nb2O5和Ta2O5进行氯化和碳氯化的动力学。计算了Nb-O-Cl和Ta-O-Cl体系反应的标准自由能变化和相稳定性图。

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《Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science》 |1997年第2期|共11页
作者
E. Allain;
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正文语种 eng
中图分类冶金技术;
关键词
五氧化钽; 五氧化铝; 碳氢作用; 动力学;

机译：五氧化钽;五氧化铝;碳氢作用;动力学;

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1. Kinetics of chlorination and carbochlorination of pure tantalum and niobium pentoxides [J] . E. Allain Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science . 1997,第2期

机译：纯钽和五氧化二铌的氯化和碳氯化反应动力学
2. Carbochlorination kinetics of tantalum and niobium pentoxides [J] . E. Allan, I. Gaballah, F. Garcia, Revista de Metalurgia . 1999,第4期

机译：五氧化二钽和五氧化二铌的碳氯化动力学
3. Carbochlorination kinetics of tantalum and niobium pentoxides [J] . E. Allain, I. GabalIah, S.Ferreira Revista de Metalurgia . 1999,第4期

机译：五氧化二钽和五氧化二铌的碳氯化动力学
4. Effect of carbon type on the chlorination of refractory oxides: carbochlorination of tantalum oxide [C] . J.Gonzalez, M.C.Ruiz Titanium Extraction and Processing Conference . 1996

机译：碳类型对耐火氧化物氯化的影响：氧化钽的碳化氯化
5. Kinetics and mechanisms of the ligand substitution reactions of cyclopentadienyl M tetracarbonyl, indenyl M tetracarbonyl, M = niobium or tantalum, and molybdenum(2) (carbon monoxide)(6) [mu-eta(5),eta(5)-cyclopentadienylide-carbon alkyl(2)-cyclopentadienylide] with tributylphosphine, triphenylphosphine and triphenylphosphite. Photo-assisted carbonylation of supercritical ethane, ethane and methane in supercritical carbon dioxide by trans-chlorocarbonylbis(trimethylphosphine)rhodium(I). [D] . Lukmanova-Kline, Dinara Maratovna. 2001

机译：动力学和机制的环戊二烯基M四羰基，茚基M四羰基，M =铌或钽和钼（2）（一氧化碳）（6）[mu-eta（5），eta（5）-cyclopentadienylide-碳烷基（2）-环戊二烯基]与三丁基膦，三苯基膦和亚磷酸三苯酯。通过反氯羰基双（三甲基膦）铑（I）在超临界二氧化碳中对超临界乙烷，乙烷和甲烷进行光辅助羰基化。
6. Influence of niobium pentoxide addition on the properties of glass ionomer cements [O] . Isadora Martini Garcia, Vicente Castelo Branco Leitune, Gabriela De Souza Balbinot, 2016

机译：五氧化二铌的添加对玻璃离聚物水泥性能的影响
7. Carbochlorination kinetics of tantalum and niobium pentoxides [O] . E. Allain, I. Gaballah, F. García, 1999

机译：钽和铌五氧化铌的碳化氯化动力学
8. Recovery of Tin, and the Production of Niobium Pentoxide and Potassium Tantalum Fluoride from a Tin Slag [R] . Iorio, G. , Tyler, M. S. 1987

机译：锡渣的回收，以及从锡渣中生产五氧化二铌和氟化钽钾

Kinetics of chlorination and carbochlorination of pure tantalum and niobium pentoxides

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