Structural and mechanical characterization of boron doped biphasic calcium phosphate produced by wet chemical method and subsequent thermal treatment

摘要

In the current study, boron doped biphasic calcium phosphate bioceramics consisting of a mixture of boron doped hydroxyapatite (BHA) and beta tricalcium phosphate (beta-TCP) of varying BHA/beta-TCP ratios were obtained after sintering stage. The effects of varying boron contents and different sintering temperatures on the BHA/beta-TCP ratios and on the sinterability of the final products were investigated. Particle sizes and morphologies of the obtained precipitates were determined using SEM. XRD and FTIR investigation were conducted to detect the boron formation in the structure of HA and quantitative analysis was performed to determine the BHA/beta-TCP ratio before and after sintering stage. In order to determine the sinterability of the obtained powders, pellets were prepared and sintered; the rates of densification were calculated and obtained results were correlated by SEM images. Also Vickers microhardness values of the sintered samples were determined. The experimental results verified that boron doped hydroxyapatite powders were obtained after sintering stage and the structure consists of a mixture of BHA and beta-TCP. As the boron content used in the precipitation stage increases, beta-TCP content of the BHA/beta-TCP ratio increases but sinterability, density and microhardness deteriorate. As the sintering temperature increases, beta-TCP content, density and microhardness of the samples increase and sinterability improves. (C) 2016 Elsevier Inc. All rights reserved.