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Breakaway properties of film formed on copper and copper alloys in erosion - corrosion by mass transfer equation

机译:铜和铜合金上形成的膜在腐蚀-腐蚀中的剥离特性通过传质方程

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Erosion-corrosion tests on copper and three types of copper alloys in a 1 wt% solution of CuCl{sub}2 were carried out at various flow velocities using a jet-in-slit testing apparatus, which is capable of reproducing various hydrodynamic conditions. A damage profile of a specimen was developed using a surface roughness meter to evaluate locally occurring damage. The damage depth rate for copper, beryllium copper, and a 70/30 copper nickel alloy increased with increasing flow velocity, and suddenly increased at a certain velocity, which is called the breakaway velocity. The breakaway velocities at the central and disturbed part of a specimen were different for each sample, indicating that the hydrodynamic conditions of the flowing solution had an effect. The damage depth rate, calculated from the mass transfer equation, which involved mass transfer in the concentration diffusion layer and in the corrosion product film, could be fitted to the experimental data, suggesting that the mass transfer equation can be applied to the evaluation of erosion-corrosion damage. The corrosion product film was exponentially broken away at velocities higher than the breakaway velocity. The breakaway properties of the corrosion product film were confirmed to be different for each material, since the power of the exponential equation was different for each sample.
机译:使用能够再现各种流体力学条件的狭缝喷射装置,以各种流速对铜和三种类型的铜合金在1wt%的CuCl {sub} 2溶液中进行腐蚀腐蚀试验。使用表面粗糙度仪评估样品的损坏情况,以评估局部发生的损坏。铜,铍铜和70/30铜镍合金的损伤深度率随着流速的增加而增加,并以一定的速度突然增加,这称为分离速度。每个样品在样品中心和受扰部分的分离速度都不同,这表明流动溶液的流体动力学条件会产生影响。根据质量传递方程计算的损伤深度率可与实验数据拟合,该损伤深度率涉及浓度扩散层和腐蚀产物膜中的质量传递,表明该质量传递方程可用于腐蚀评估-腐蚀损坏。腐蚀产物膜以高于脱离速度的速度指数地脱离。每种产品的腐蚀产物膜的断裂特性都不同,这是因为每种样品的指数方程的功效都不同。

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