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Parameters governing the reduction of oxide layers on Inconel 617 in impure VHTR He atmosphere

机译:在不纯的VHTR He气氛中控制Inconel 617上氧化物层还原的参数

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The very high temperature reactor (VHTR) has been selected as among the Generation IV nuclear power system. The coolant, namely helium, has been shown to contain low level of oxidizing as well as carbon-bearing impurities (such as H{sub}2, CO (and CO{sub}2), CH{sub}4, N{sub}2 ranging from a few microbars to hundreds of microbars and water vapour in the microbar range) that can interact with metals at high temperature. In this specific gas phase, there is a competition between the formation of protective oxide scales and deleterious reactions towards carbon. A possible oxide layer reduction could be observed in a particular case detailed in this paper. This destruction of the oxide can imply consequences on the behaviour of the alloy as strong carburization or deep internal oxidation could occur. The influence of the level of impurities was analysed through a parametric approach. The experiments were carried out in a purpose-designed device that allows the control of low impurity partial pressures.
机译:高温反应堆(VHTR)已被选为第四代核电系统。冷却剂,即氦气,已被证明含有低水平的氧化以及含碳杂质(例如H {sub} 2,CO(和CO {sub} 2),CH {sub} 4,N {sub } 2,范围从几微巴到几百微巴,以及在高温下可以与金属相互作用的水蒸气(在微巴范围内)。在这种特定的气相中,保护性氧化皮的形成与对碳的有害反应之间存在竞争。在本文详细介绍的特定情况下,可以观察到可能的氧化物层减少。氧化物的这种破坏可能暗示合金的行为,因为可能发生强渗碳或深层内部氧化。通过参数方法分析了杂质含量的影响。实验是在专门设计的设备中进行的,该设备可以控制低杂质分压。

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