Novel poly(butylene succinate)-based ionomers with sulfonated succinate units: Synthesis, morphology, and the unique nucleation effect on crystallization

摘要

Poly(butylene succinate) (PBS) and PBS-based ionomers (PBSi's) with 0.3 and 1.2 mol-% of sodium sulfonated succinate unit were synthesized. The existence of ionic aggregates in the ionomer matrices was indicated by melt viscosity and glass transition data. It seems that the ionic aggregates have two opposing roles in crystallization: one is the induction of nucleation and the other is the interference with lamellar growth. Because of these two contrary effects, the crystallisation behaviour of the ionomers exhibited measurably different cooling rate dependencies with ionic content.