Peripheral cyanohexyl substituent in wide bandgap polymer: Increase the electron injection property for blue phosphorescence light emitting device

摘要

Novel blue phosphor host, PCNCzSi, using 3,6-linked carbazole with δ-π tetraphenylsilane segment as the main chain modified by peripheral cyanohexyl group was designed. The Si-carbazole backbone entitles the polymer with wide bandgap, high E_T and good hole transporting ability. The introduction of peripheral CN group with high electron affinity enhances the electron injecting property of the polymer revealed by electron-only device and UPS measurement. Highly efficient spin-coated phosphorescent polymer light-emitting device, using PCNCzSi as the host for blue iridium complex, FIrpic, was realized. The maximum luminous efficiency and maximum external quantum efficiency of the device were 15 cd/A and 6.7%, respectively, which are very high values for blue phosphorescent device using polymers as hosts as known. Cyano group, which possesses strong electron-withdrawing property, was attached on the hexyl side chain to obtain wide band gap polymer, PCNCzSi. Highly efficient spin-coated phosphorescent polymer light-emitting device, using PCNCzSi as the host for blue iridium complex FIrpic was prepared, and the maximum luminous efficiency and maximum external quantum efficiency of the devices were reached to 15 cd/A and 6.7%, respectively.