Cyclization of N-Allyl-5-allyl-5-hydroxylactams to 8a-Hydroxy-l,5,8,8a-tetrahydro-2H-indolizin-3-ones Using Grubbs' Catalyst

Seok Won Kang; Yong Hoon Kim; Sung Hoon Kim

首页> 外文期刊>Bulletin of the Korean Chemical Society >Cyclization of N-Allyl-5-allyl-5-hydroxylactams to 8a-Hydroxy-l,5,8,8a-tetrahydro-2H-indolizin-3-ones Using Grubbs' Catalyst

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Cyclization of N-Allyl-5-allyl-5-hydroxylactams to 8a-Hydroxy-l,5,8,8a-tetrahydro-2H-indolizin-3-ones Using Grubbs' Catalyst

机译：N-烯丙基-5-烯丙基-5-羟基内酰胺使用格拉布斯催化剂环化为8a-羟基-1,5,8,8a-四氢-2H-吲哚嗪-3-酮

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摘要

A short and highly efficient synthetic method to prepare synthetically useful tetrahydroindolizinone derivatives from the ring-closing metathesis of N-allyl-5-allyl-5-hydroxylactams is described.

机译：描述了一种由N-烯丙基-5-烯丙基-5-羟基内酰胺的开环易位制备合成上有用的四氢吲哚嗪酮衍生物的短而高效的合成方法。

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《Bulletin of the Korean Chemical Society》 |2008年第4期|共3页
作者
Seok Won Kang; Yong Hoon Kim; Sung Hoon Kim;
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正文语种 eng
中图分类化学工业;
关键词
Grubbs' catalyst; Ring-closing metathesis (RCM); Tetrahydroindolizinone; N-Acyliminium ion;

机译：格拉布斯催化剂;闭环复分解法（RCM）;四氢吲哚嗪酮;N-酰基亚胺离子;

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1. Cyclization of N-Allyl-5-allyl-5-hydroxylactams to 8a-Hydroxy-l,5,8,8a-tetrahydro-2H-indolizin-3-ones Using Grubbs' Catalyst [J] . Seok Won Kang, Yong Hoon Kim, Sung Hoon Kim Bulletin of the Korean Chemical Society . 2008,第4期

机译：N-烯丙基-5-烯丙基-5-羟基内酰胺使用格拉布斯催化剂环化为8a-羟基-1,5,8,8a-四氢-2H-吲哚嗪-3-酮
2. Atom Transfer Radical Cyclization of Trichloroacetamides to Electron-Rich Acceptors Using Grubbs' Catalysts:Synthesis of the Tricyclic Framework of FR901483 [J] . Fa?za Diaba, Agustín Martínez-Laporta, Josep Bonjoch The Journal of Organic Chemistry . 2014,第19期

机译：使用Grubbs催化剂将三氯乙酰胺的原子转移到富含电子的受体的自由基环化：FR901483的三环框架的合成
3. Synthesis, reaction, and recycle of light fluorous Grubbs-Hoveyda catalysts for alkene metathesis [J] . Matsugi M, Curran DP The Journal of Organic Chemistry . 2005,第5期

机译：用于烯烃复分解的轻质氟Grubbs-Hoveyda催化剂的合成，反应和回收
4. New N-Heterocyclic Carbene Ligands in Grubbs and Hoveyda-Grubbs Catalysts [C] . Stijn Monsaert, Nele Ledoux, Renata Drozdzak, NATO Advanced Study Institute on Green Metathesis Chemistry: Great Challenges in Synthesis, Catalysis and Nanotechnology . 2010

机译：Grubbs和Hoveyda-Grubbs催化剂的新的N-杂环卡宾配体
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Hoveyda–Grubbs catalysts with an N→Ru coordinate bond in a six-membered ring. Synthesis of stable industrially scalable highly efficient ruthenium metathesis catalysts and 2-vinylbenzylamine ligands as their precursors [O] . Kirill B Polyanskii, Kseniia A Alekseeva, Pavel V Raspertov, 2019

机译：Hoveyda–Grubbs催化剂在六元环中具有N→Ru配位键。稳定工业规模可扩展的高效钌复分解催化剂和2-乙烯基苄胺配体的合成
7. Isomerization and cycloisomerization using Grubbs complex as the precatalyst--Identification of the active species and application to the synthesis of heterocycles-- [O] . 寺田幸芳, テラダユキヨシ, Terada Yukiyoshi 100

机译：Isomerization and cycloisomerization using Grubbs complex as the precatalyst--Identification of the active species and application to the synthesis of heterocycles--
8. Dynamic Chemical and Structural Changes of Heterogeneous Catalysts Observed in Real Time: From Catalysis-Induced Fluxionality to Catalytic Cycles. [R] . Rioux, R. M. 2014

机译：实时观察到的非均相催化剂的动态化学和结构变化：从催化诱导的通量到催化循环。

Cyclization of N-Allyl-5-allyl-5-hydroxylactams to 8a-Hydroxy-l,5,8,8a-tetrahydro-2H-indolizin-3-ones Using Grubbs' Catalyst

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