Highly regioselective rhenium-catalyzed hydrosilylation of styrenes

Zhao WG; Huan R

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Highly regioselective rhenium-catalyzed hydrosilylation of styrenes

机译：苯乙烯的高区域选择性hydro催化的氢化硅烷化

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The addition reaction of silanes to styrenes is efficiently catalyzed by ReBr(CO)5 in toluene heated at 120 degrees C and selectively affords anti-Markovnikov adducts in good to high yields. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

机译：在加热到120摄氏度的甲苯中，通过ReBr（CO）5有效地催化硅烷与苯乙烯的加成反应，并选择性地以高收率或高收率提供反马氏复合物。（（C）Wiley-VCH Verlag GmbH＆Co.KGaA，69451 Weinheim，Germany，2006）。

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《European journal of organic chemistry》 |2006年第24期|共4页
作者
Zhao WG; Huan R;
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正文语种 eng
中图分类有机化学;
关键词
catalysis; hydrosilylation; regioselectivity; rhenium; styrene; TERMINAL ALKYNES; ANTI-MARKOVNIKOV; METAL-COMPLEXES; TRANS ADDITION; SELECTIVE HYDROSILYLATION; RUTHENIUM COMPLEXES; RHODIUM; MECHANISM; HYDROSILATION; EFFICIENT;

机译：催化;氢化硅烷化;区域选择性;r;苯乙烯;末端烷基;抗-MARKOVNIKOV;金属络合物;加成;选择性加氢甲硅烷基化;钌络合物;铑;机理;加氢敏化;高效;

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专利

1. Highly regioselective rhenium-catalyzed hydrosilylation of styrenes [J] . Zhao WG, Huan R European journal of organic chemistry . 2006,第24期

机译：苯乙烯的高区域选择性hydro催化的氢化硅烷化
2. Oligomerization and regioselective hydrosilylation of styrenes catalyzed by cationic allyl nickel complexes bearing allylphosphine ligands [J] . Hyder I, Jimenez-Tenorio M, Puerta MC, Dalton transactions: An international journal of inorganic chemistry . 2007,第28期

机译：带有烯丙基膦配体的阳离子烯丙基镍配合物催化苯乙烯的低聚和区域选择性氢化硅烷化
3. Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation [J] . Meng-Yang Hu, Qiao He, Song-Jie Fan, Nature Communications . 2018,第1期

机译：具有1,10-菲咯啉骨架的配体用于高度区域选择性的铁催化的烯烃氢化硅烷化
4. Helical Polymer-Based Monodentate Phosphine Ligand for Asymmetric Hydrosilylation of Styrenes [C] . Takeshi Yamamoto, Akinori Ueda, Michinori Suginome Symposium on Organometallic Chemistry . 2007

机译：基于螺旋聚合物的单透露膦配体，用于苯乙烯的不对称氢化硅烷化
5. I. Highly regioselective diastereoselective directed hydroformylation of allyl ethers. II. Highly practical and enantioselective ligands for copper-catalyzed conjugate addition. [D] . Krauss, Isaac Jonathan. 2003

机译：I.烯丙基醚的高度区域选择性非对映选择性定向加氢甲酰化。二。用于铜催化共轭加成的高度实用和对映选择性配体。
6. Ligands with 110-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation [O] . Meng-Yang Hu, Qiao He, Song-Jie Fan, -1

机译：具有110-菲咯啉骨架的配体可用于高度区域选择性的铁催化的烯烃氢化硅烷化
7. Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation [O] . Meng-Yang Hu, Qiao He, Song-Jie Fan, 2018

机译：具有1,10菲咯啉支架的配体，用于高度区域选择性铁催化烯烃氢化硅烷化
8. Thermo Stability of Highly Sulfonated Poly(Styrene-Isobutylene-Styrene) Block Copolymers: Effects of Sulfonation and Counter-Ion Substitution [R] . Sloan, J. M., Suleiman, D., Napadensky, E., 2008

机译：高磺化聚（苯乙烯 - 异丁烯 - 苯乙烯）嵌段共聚物的热稳定性：磺化和反离子取代的影响

Highly regioselective rhenium-catalyzed hydrosilylation of styrenes

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