Copper(II)-Catalyzed Oxidation of Alcohols to Carbonyl Compounds with Hydrogen Peroxide

Subbarayan Velusamy; Tharmalingam Punniyamurthy

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Copper(II)-Catalyzed Oxidation of Alcohols to Carbonyl Compounds with Hydrogen Peroxide

机译：铜（II）-过氧化氢催化的醇氧化为羰基化合物

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摘要

Copper(II) complex 1 efficiently catalyses the oxidation of alcohols to the corresponding carboxylic acid analogues and ketones in the presence of H_2O_2 in high yields.

机译：在H_2O_2存在下，铜（II）配合物1有效地催化了醇氧化成相应的羧酸类似物和酮的反应，产率很高。

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《European journal of organic chemistry》 |2003年第20期|共3页
作者
Subbarayan Velusamy; Tharmalingam Punniyamurthy;
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正文语种 eng
中图分类有机化学;
关键词
oxidation; alcohols; catalysts; copper(II) complexes; hydrogen peroxide;

机译：氧化;醇;催化剂;铜（II）配合物;过氧化氢;

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专利

1. Copper(II)-Catalyzed Oxidation of Alcohols to Carbonyl Compounds with Hydrogen Peroxide [J] . Subbarayan Velusamy, Tharmalingam Punniyamurthy European journal of organic chemistry . 2003,第20期

机译：铜（II）-过氧化氢催化的醇氧化为羰基化合物
2. Oxidation of Alcohols by Hydrogen Peroxide Catalyzed by Trinuclear Copper(II) complex [Cu_3(slmh)(μ-Cl)_2(CH_3OH)_3].0.5CH_3OH derived from Disalicylaldehyde Malonoyldihydrazone [J] . Sunshine D. Kurbah, Arvind Kumar, Sankey Shangpung, Current Organocatalysis . 2017,第1期

机译：通过三核铜（II）络合物催化的过氧化氢氧化醇氧化[Cu_3（SLMH）（μ-Cl）_2（CH_3OH）_3] .0.5CH_3OH衍生自脱盐甘油醛丙二酰基肼
3. Oxidation of benzyl alcohols to the corresponding carbonyl compounds catalyzed by copper (II) meso-tetra phenyl porphyrin as cytochrome P-450 model reaction [J] . Rahmatolah Rahimi, Ensieh Gholamrezapor, Mohammad Reza Naimi-jamal Inorganic Chemistry Communications . 2011,第10期

机译：铜（II）介孔四苯基卟啉催化的苄醇氧化为相应的羰基化合物作为细胞色素P-450模型反应
4. Selectively Catalyzed Oxidation of Benzyl Alcohol by Fe~(III)–TAML/Hydrogen Peroxide [C] . Ran Li, Ge Wang, Yanchun Liu, International Conference on Applied Mechanics and Materials . 2015

机译：通过Fe〜（III）-Taml /氢过氧化氢选择性地催化苄醇的氧化
5. Oxidation of copper(II) complexes of histidine-containing tri- and tetrapeptides by L-ascorbic acid and hydrogen peroxide to copper(III) and its subsequent decay to geometric isomers of alpha,beta-dehydrohistidyl tautomers. [D] . Burke, Samantha Kaye. 2003

机译：L-抗坏血酸和过氧化氢将含组氨酸的三肽和四肽的铜（II）络合物氧化为铜（III），随后分解为α，β-脱氢组氨酸互变异构体的几何异构体。
6. Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition [O] . In Su Kim, Ming-Yu Ngai, Michael J. Krische -1

机译：对映选择性铱通过乙酸烯丙酯的转移加氢偶联从醇或醛的氧化级催化羰基烯丙基化：脱除羰基加成中的手性改性烯丙基金属试剂
7. Transition metal-free oxidation of benzylic alcohols to carbonyl compounds by hydrogen peroxide in the presence of acidic silica gel [O] . Hossein Ghafuri 2015

机译：在酸性硅胶存在下，通过过氧化氢将苄醇过渡金属无氧化成羰基化合物
8. Kinetics of the Oxidation of Hydrazine by Hydrogen Peroxide,Catalyzed by Copper(II). [R] . wellman,carl r. ward, j. richard 1975

机译：铜（Ⅱ）催化过氧化氢氧化肼的动力学。

Copper(II)-Catalyzed Oxidation of Alcohols to Carbonyl Compounds with Hydrogen Peroxide

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