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首页> 外文期刊>Ionics >Influence of the Thickness of Sputter-Deposited Platinum Films on the Electrochemical Promotion of Propane Combustion
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Influence of the Thickness of Sputter-Deposited Platinum Films on the Electrochemical Promotion of Propane Combustion

机译:溅射沉积铂膜的厚度对丙烷燃烧电化学促进的影响

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8 to 120 nm-thick Pt coatings were sputter-deposited on Yttria-Stabilised Zirconia(YSZ)membranes,17 mm in diameter,by magnetron sputtering of a Pt target at low pressure(0.3 Pa).The catalytic activity of propane combustion under open-circuit conditions is first measured near to the stoichiometry(0.2%C_3H_8/l%O_2)and shows that the coatings present a rather high catalytic activity.Close-circuit measurements were finally performed at 337 deg C and 400 deg C.They show that rather high faradaic efficiencies in the range 10~6 can be reached as soon as the Pt film is thick enough to allow a bias of its whole area.
机译:通过在低压(0.3 Pa)下磁控溅射Pt靶,在直径为17 mm的氧化钇稳定氧化锆(YSZ)膜上溅射沉积8至120 nm厚的Pt涂层。首先在接近化学计量比(0.2%C_3H_8 / l%O_2)的条件下测量电路条件,结果表明该涂层具有较高的催化活性,最后在337摄氏度和400摄氏度下进行了闭路测量。只要Pt膜的厚度足以允许整个区域的偏差,就可以在10〜6范围内达到相当高的法拉第效率。

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