The microwave synthesis of platinum(II) phosphine complexes

摘要

The microwave synthesis of a series of platinum(II) phosphine complexes is reported. The complexes dppePtCl2 (dppe = bis(diphenylphosphino) ethane), dpppPtCl_2 (dppp = bis(diphenylphosphino)propane), dppmPtCl_2 (dppm = bis(diphenylphosphino)methane) and cis-(Ph _3P)_2PtCl_2 are synthesized from the reaction of potassium tetrachloroplatinate(II) and the phosphine. The isolated yields are 65% or better.