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Numerical Investigation and Experimental Observation of Extrudate Swell for Viscoelastic Polymer Melts

机译:粘弹性聚合物熔体挤出胀大的数值研究与实验观察

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In the present research die swell phenomenon is investigated for the viscoelastic polymer melts both experimentally and by developing a mathematical model in a circular die for high impact polystyrenes (HIPS), high density polyethylene (HDPE), low density polyethylene (LDPE) and linear low density polyethylene (LLDPE). Die swell is generally attributed to the fluid stress field when the fluid flows in a die. The Leonov-like equations as a conformational model are solved simultaneously with dynamic equation of momentum transfer to predict the stress field for a viscoelastic fluid in a circular die. The average molecular weight, the polymer relaxation time and the polymer mobility tensors are determined using the experimental measurements of shear viscosity. Then, based on those data, a model is developed. The results predicted by the model for flow stress field are then used to calculate die swell ratio by Tanner's analytical model. Die swell ratio is also found out experimentally using a capillary rhe-ometer for the samples. Comparison of the die swell results predicted by the model and measured experimentally show very good agreement for the polymers.
机译:在本研究中,通过实验和通过开发用于高抗冲聚苯乙烯(HIPS),高密度聚乙烯(HDPE),低密度聚乙烯(LDPE)和线性低聚物的圆形模具中的粘弹性聚合物熔体的模膨胀现象进行了研究。密度聚乙烯(LLDPE)。当流体在模具中流动时,模具膨胀通常归因于流体应力场。同时求解作为结构模型的列昂诺夫方程和动量传递动力学方程,以预测圆形模具中粘弹性流体的应力场。使用剪切粘度的实验测量值确定平均分子量,聚合物弛豫时间和聚合物迁移率张量。然后,基于这些数据,开发模型。该模型针对流变应力场预测的结果随后通过Tanner的解析模型用于计算模具的溶胀率。还使用毛细管流变仪通过实验发现了样品的溶胀率。通过模型预测和实验测量的模头溶胀结果的比较表明,该聚合物具有很好的一致性。

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