首页> 外文期刊>International Journal of Quantum Chemistry >Novel organic-inorganic layered compounds derived from simple coordination building blocks: Synthesis and structural characterization of (H3NCH2CH2NH3)[Fe(C2O4)MoO4] and Fe(H2NCH2CH2NH2)MoO4
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Novel organic-inorganic layered compounds derived from simple coordination building blocks: Synthesis and structural characterization of (H3NCH2CH2NH3)[Fe(C2O4)MoO4] and Fe(H2NCH2CH2NH2)MoO4

机译:由简单配位基团衍生的新型有机-无机层状化合物:(H3NCH2CH2NH3)[Fe(C2O4)MoO4]和Fe(H2NCH2CH2NH2)MoO4的合成和结构表征

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摘要

Two new hybrid organic-inorganic compounds (H3NCH2CH2 NH3)[Fe(C2O4)MoO4] (1) and Fe(H2NCH2CH2NH2) (2) were synthesized by the hydrothermal reaction between Fe(C2O2) . 2H(2)O, molybic acid, and ethylenediamine, The structure of 1 consists of 2-D layers formed by [Fe(C2O4)MoO4](2-) nets with H3N+CH2CH2N+H3 dications situated in the gaps, The structure of 2 features a double-layered structure formed by FeMoO4 units that are capped by cis-coordinated H2NCH2CH2NH2 molecules. (C) 2000 Academic Press. [References: 25]
机译:通过Fe(C2O2)之间的水热反应,合成了两种新的杂化有机-无机化合物(H3NCH2CH2 NH3)[Fe(C2O4)MoO4](1)和Fe(H2NCH2CH2NH2)(2)。 2H(2)O,甲酸和乙二胺,1的结构由[Fe(C2O4)MoO4](2-)网形成的二维层,其中H3N + CH2CH2N + H3标记位于间隙中,结构2的特征是由FeMoO4单元形成的双层结构,该单元由顺式配位的H2NCH2CH2NH2分子封端。 (C)2000年学术出版社。 [参考:25]

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