Theoretical Study of the Rydberg Spectra of Chemically Relevant Isovalent Radicals

摘要

In the present work we have studied the Rydberg spectroscopic behavior of the CH_3 and SiH_3 isovalent radicals. The molecular-adapted quantum defect orbital (MQDO) method has been employed in our calculations, which have been extended to the radicals' isolated central atoms, C and Si. The similarities observed between the intensities of analogous transitions in the atoms and the corresponding radicals have not only served the purpose of assessing the quality of our calculations but also offer some potential practical usefulness.