Synthesis, crystal structure and luminescent properties of new tris-β-diketonate Eu(III) complex with thiadiazolophenanthroline derivative ligand

摘要

Herein we describe the synthesis, characterization and spectroscopic properties of the complex tris-(thenoyltrifluoroacetonate)([1,2,5]thiadiazolo[3,4-f][l,10]phenanthroline) europium(III) acetonitrile solvate, [Eu(TTA)3TDPHEN] 1.5CH3CN, where TTA = 2-thenoyl trifluoroacetone and TDPHEN = [1,2,5]thi-adiazolo[3,4-f][1,10] phenanthroline. X-ray crystallography reveals that it is an eight-coordinate Eu(III) complex containing three β-diketonate chelates and one N,N'-bidentate ligand, [1,2,5] thiadiazolo[3,4-f][1,10] phenanthroline. The excitation at 340 nm of the europium complex in a solution of acetonitrile, and at room-temperature, showed the typical Eu(III) red emission as a sharp band at 611 nm, characteristic of Eu(III) due to the transition ~5D0 →~7F2. This complex also showed red emission in the solid state phase (λ_(em) = 612 nm).