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A New Modified Method to Obtain a High Melt Index of PLA Polymer and Preparation of Melt-Blown Nonwoven Cloth

机译:一种获得高熔融指数PLA聚合物的改性方法及熔喷非织造布的制备方法

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Abstract Due to the low melt index of polylactic acid (PLA) polymer, it is difficult to melt-blown processing. Here, a new modified method to obtain a high melt index of PLA polymer and melt-blown nonwoven cloth was studied. PLA polymers are modified by the thermally degraded method of stannous octoate (Sn(Oct)2) and polyethylene glycol (PEG) to obtain a high melt index (1054?g/10?min) in comparison with a low melt index (23?g/10?min) of original unmodified PLA polymer. The fiber of modified PLA polymer melt-blown cloth is obviously thinner, having sub-micron fibers, the smallest fiber is about 200?nm. From our test, modified PLA polymer melt-blown cloth has good oil absorption, oil–water separation, and potential air filtration property. In terms of degradation, the modified PLA polymer melt-blown cloth showed excellent degradation performance in basic aqueous solutions at 55?°C at pH 12, reaching a degradation rate of around 95 at 60?h.
机译:摘要 由于聚乳酸(PLA)聚合物的熔融指数低,熔喷加工困难。本文研究了一种新的改性方法,以获得PLA聚合物和熔喷无纺布的高熔融指数。通过辛酸亚锡(Sn(Oct)2)和聚乙二醇(PEG)的热降解方法对PLA聚合物进行改性,以获得高熔融指数(1054?g/10?min),而原始未改性的PLA聚合物的熔融指数(23?g/10?min)较低。改性PLA聚合物熔喷布的纤维明显较薄,具有亚微米级的纤维,最小的纤维约为200?nm。从我们的测试来看,改性PLA聚合物熔喷布具有良好的吸油性、油水分离性和潜在的空气过滤性能。在降解方面,改性PLA聚合物熔喷布在55°C、pH 12的碱性水溶液中表现出优异的降解性能,在60?h时降解率达到95%左右。

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