Review of molecular imprinting polymer: basic characteristics and removal of phenolic contaminants based on the functionalized cyclodextrin monomer

摘要

Cyclodextrins (CDs) are formed of starch molecules that are linked together in a cyclic ring. They are composed of five or more (1, 4) connected D-glucopyranoside units. CDs have toroidal, hollow truncated cone structures with exterior hydrophilic edges and internal hydrophobic cavities. The numerous hydroxyl groups available in cyclodextrins are active sites capable of forming various sorts of connections. They can be cross-linked or derived to generate monomers able to form branching or linear networks. Furthermore, they can form inclusion complexes with a variety of guest molecules, including organic and inorganic molecules, thus changing their physicochemical properties, The modification of the imprinting method could produce molecularly imprinted polymers that are stable, dependable, long-lasting, selective, and cost-effective. As a result, molecularly imprinted polymers are becoming increasingly popular in chemical separation and analysis. As found in previous studies, the monomers of cyclodextrins used in molecular imprinting have a higher binding impact on target molecules. The purpose of this study is to highlight the application of imprinting technology utilizing cyclodextrins as a valuable functional monomer in the remediation of phenolic compounds by examining and assessing relevant works published in the literature. (C) 2022 Society of Chemical Industry (SCI).