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Capillary electrophoretic application of 1-alkyl-3-methylimidazolium-basedionic liquids

机译:1-烷基-3-甲基咪唑鎓类离子液体的毛细管电泳应用

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Ionic substances with melting points at or close to room temperature are referred to as ionic liquids. Interest in ionic liquids for their potential in different chemical processes is increasing, because they are environmentally benign and are good solvents for a wide range of both organic and inorganic materials. In this study, a capillary electrophoretic method for resolving phenolic compounds found in grape seed extracts is reported. The method, Mi which 1-alkyl-3-methylimidazolium-based ionic liquids are used as the running electrolytes, is simple and reproducible. The separation mechanism seems to involve association between the imidazolium cations and the polyphenols. The role of the alkyl substituents on the imidazolium cations was investigated and will be discussed.
机译:熔点在室温或接近室温的离子物质称为离子液体。人们对离子液体在不同化学过程中的潜力越来越感兴趣,因为它们对环境无害,并且是适用于各种有机和无机材料的良好溶剂。在这项研究中,报道了一种毛细管电泳方法,用于分离葡萄籽提取物中发现的酚类化合物。使用基于1-烷基-3-甲基咪唑鎓的离子液体作为运行电解质的方法简单且可重复。分离机理似乎涉及咪唑鎓阳离子与多酚之间的缔合。研究了烷基取代基在咪唑阳离子上的作用,并将进行讨论。

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