首页> 外文学位 >Micromolding in capillaries: A study of wetting and spreading of liquids in rectangular capillaries and applications to materials science.
【24h】

Micromolding in capillaries: A study of wetting and spreading of liquids in rectangular capillaries and applications to materials science.

机译:毛细管中的微成型:矩形毛细管中液体的润湿和扩散研究及其在材料科学中的应用。

获取原文
获取原文并翻译 | 示例

摘要

Micromolding in capillaries (MIMIC) is a technique of patterning a surface of a substrate with micrometer- and submicrometer-scale structures. An elastomeric mold made of poly(dimethylsiloxane) and having relief features in its surface is placed on a support, and contact between the elastomer and the substrate forms a network of interconnected channels. A fluid--a precursor to a polymer, a solution, or a suspension of the material to be patterned--fills these channels by capillary action. After the material in the fluid has crosslinked, crystallized, cured, adhered, or deposited onto the surface of the substrate, the elastomeric component is removed. The microstructures remain on the surface in the pattern complementary to that present in the mold.; In Chapter 2, MIMIC has been used to study the dynamics of imbibition of liquids in rectangular capillaries formed between the elastomeric mold and self-assembled monolayers (SAMs) of alkanethiolates on gold. The dynamic shapes of the liquids in capillaries, formed on SAMs having different interfacial free energies ({dollar}gammasb{lcub}rm sv{rcub}){dollar} are examined as crosslinked, solid polymers using microscopies. The shape of the imbibing liquid on a SAM with low {dollar}rmgammasb{lcub}sv{rcub}{dollar} involves precursor structures that precede macroscopic flow; on high {dollar}rmgammasb{lcub}sv{rcub}{dollar}, imbibition occurs without the precursor structures. Rates of capillary imbibition are linearly correlated to static advancing contact angles of liquids on different SAMs. Chapter 2 describes applications of MIMIC in fabrication of microstructures of organic polymers, inorganic and organic salts, ceramics, metals by electroless deposition, and crystalline arrays of microspheres. Chapter 3 examines the fabrication of polymeric structures and free-standing films fabricated from filling channels formed between two elastomeric masters, both of which had relief patterns on their surfaces. Chapter 4 describes the use of MIMIC in fabrication of patterned, crystalline arrays of polymeric microspheres and presents a mechanism that explains the process of crystallization.
机译:毛细管微成型(MIMIC)是一种使用微米级和亚微米级结构对衬底表面进行构图的技术。将由聚(二甲基硅氧烷)制成并在其表面具有凸纹特征的弹性体模具放置在支撑体上,并且弹性体和基材之间的接触形成相互连接的通道的网络。流体-待形成图案的材料的聚合物,溶液或悬浮液的前体-通过毛细作用填充这些通道。在流体中的材料已经交联,结晶,固化,粘附或沉积到基底表面上之后,去除弹性体组分。微观结构以与模具中存在的图案互补的图案保留在表面上。在第2章中,使用MIMIC研究了弹性模子与硫链烷酸酯在金上的自组装单层(SAM)之间形成的矩​​形毛细管中液体的吸收动力学。使用微影技术检查了在具有不同界面自由能(SAM)的SAM上形成的毛细管中液体的动态形状,它们是交联的固态聚合物。具有较低的美元的SAM上的吸收液体的形状涉及宏观流动之前的前体结构;在{dollar} rmgammasb {lcub} sv {rcub} {dollar}较高的情况下,没有前体结构就会发生吸收。毛细管吸收速率与液体在不同SAM上的静态前进接触角线性相关。第2章介绍了MIMIC在有机聚合物,无机盐和有机盐,陶瓷,通过无电沉积的金属以及微球晶体阵列的微结构制造中的应用。第3章探讨了由两个弹性母盘之间形成的填充通道制造的聚合物结构和自支撑膜的制造,这两个弹性模盘的表面均具有凹凸图案。第4章介绍了MIMIC在制造聚合物微球图案化晶体阵列中的应用,并介绍了一种解释结晶过程的机理。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号