Synthesis, Structure, High-Resolution Spectroscopy, and Laser Chemistry of Fluorooxirane and 2,2-[~2H_2]-Fluorooxirane

摘要

Fundamental questions concerning symmetry, structure, and dynamics of chiral molecules beyond classical structural concepts may in future be answered by spectroscopy and laser chemical investigations. For this purpose, small chiral molecules that canbe investigated by reaction dynamics and by gas-phase IR and UV spectroscopy with rotational resolution have to be found. Only few examples of this type have been reported, for instance CHBrCIF'31 or the substituted thiiran-1-oxides.