Highly sensitive and rapid determination of sunset yellow in drinks using a low-cost carbon material-based electrochemical sensor

摘要

Starting from simple graphite flakes, an electrochemical sensor for sunset yellow monitoring is developed by using a very simple and effective strategy. The direct electrochemical reduction of a suspension of exfoliated graphene oxide (GO) onto a glassy carbon electrode (GCE) surface leads to the electrodeposition of electrochemically reduced oxide at the surface, obtaining GCE/ERGO-modified electrodes. They are characterized by cyclic voltammetry (CV) measurements and field emission scanning electron spectroscopy (FE-SEM). The GCE/ERGO electrode has a high electrochemically active surface allowing efficient adsorption of SY. Using differential pulse voltammetry (DPV) technique with only 2 min accumulation, the GCE/ERGO sensor exhibits good performance to SY detection with a good linear calibration for concentration range varying 50-1000 nM (R-2=0.996) and limit of detection (LOD) estimated to 19.2 nM (equivalent to 8.9 mu g L-1). The developed sensor possesses a very high sensitivity of 9 mu A/mu M while fabricated with only one component. This electrochemical sensor also displays a good reliability with RSD value of 2.13% (n=7) and excellent reusability (signal response change <3.5% after 6 measuring/cleaning cycles). The GCE/ERGO demonstrates a successful practical application for determination of sunset yellow in commercial soft drinks.