Determination of the Isotopic Composition of Gadolinium Using Multicollector Inductively Coupled Plasma Mass Spectrometry

摘要

In this study, we report independent measurements of all stable isotope ratios of gadolinium. Our study employs multicollector inductively coupled plasma mass spectrometry (MC-ICPMS) with National Research Council Canada (NRC) HALF-1 isotopic hafnium standard as a primary calibrator and surveys four commercial gadolinium materials, including a NRC candidate isotopic reference material, GADS-1. The isotopic composition of gadolinium is determined using the regression model without reliance on conventional normalizing isotope ratios or mass-dependent isotope ratio correction models. In this work, all gadolinium isotope ratios were obtained from Gd-160/Gd-158 which, in turn, was measured from hafnium Hf-1(78)/Hf-1(77) either directly or indirectly through Er-167/ Er-166. The latter approach was used for the final determination of gadolinium isotopic composition, as it provides smaller combined uncertainty. We report high-precision measurements of the isotopic composition of gadolinium, which support a revised standard atomic weight. Isotope amount ratios of R-152/158 = 0.008 20(2)(k=1 ) R-154/158 = 0.087 98(12)(k=1), R-155/158 = 0.596 81 (63)(k=)(1), R-166/158 98(12)(k=1), R-155/158 = 0.825 08(57)(k=1), R-157(/158) = 0.630 60(22)(k=1), and R-160/158 = 0.879 10(60)(k=1) and the atomic weight of A(r)(Gd) = 157.2502(6)(k=1) were obtained for gadolinium in GADS-1.