Organosulfur Compounds:Electrophilic Reagents in Transition-Metal-Catalyzed Carbon-Carbon Bond-Forming Reactions

摘要

Transition-metal-catalyzed carbon-carbon bond-forming reactions are among the most powerful methods in organic synthesis and play a crucial role in modern materials science and medicinal chemistry.Recent developments in the area of ligands and additives permit the cross-coupling of a large variety of reactants,including inexpensive and readily available sulfonyl chlorides.Their desulfitative carbon-carbon cross-coupling reactions (Negishi,Stille,carbonylative Stille,Suzuki-Miyaura,and Sonogashira-Hagihara-type cross-couplings and Mizoroki-Heck-type arylations) are reviewed together with carbon-carbon cross-coupling reactions with other organosulfur compounds as electrophilic reagents.