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Sulfur(IV)‐Mediated Unsymmetrical Heterocycle Cross‐Couplings

机译：硫（IV）介导的非对称杂环交叉联轴器

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Abstract >Despite the tremendous utilities of metal‐mediated cross‐couplings in modern organic chemistry, coupling reactions involving nitrogenous heteroarenes remain a challenging undertaking – coordination of Lewis basic atoms into metal centers often necessitate elevated temperature, high catalyst loading, etc. Herein, we report a sulfur (IV) mediated cross‐coupling amendable for the efficient synthesis of heteroaromatic substrates. Addition of heteroaryl nucleophiles to a simple, readily‐accessible alkyl sulfinyl (IV) chloride allows formation of a trigonal bipyramidal sulfurane intermediate. Reductive elimination therefrom provides bis‐heteroaryl products in a practical and efficient fashion. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> <P>尽管现代有机化学中的金属介导的交叉联轴器具有巨大的实用性，但涉及含氮异质的偶联反应仍然是一个挑战性的承诺 - Lewis碱性原子与金属中心的协调通常需要升高的温度，高催化剂负载等。我们报告了硫磺（IV）介导的交叉偶联，可用于有效合成杂芳族底物。向简单的易于可接近的烷基磺酰基（IV）氯化物加入杂芳基亲核试剂允许形成Trigonal的双嘧酰胺硫氧中间体。其中减少消除以实用和高效的方式提供双杂芳基产品。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Min&option=202" target="_blank" rel="nofollow">Zhou Min;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tsien Jet&option=202" target="_blank" rel="nofollow">Tsien Jet;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qin Tian&option=202" target="_blank" rel="nofollow">Qin Tian;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of BiochemistryThe University of Texas Southwestern Medical Center5323 Harry Hines Boulevard Dallas TX 75390-9038 USA;</p> <p>Department of BiochemistryThe University of Texas Southwestern Medical Center5323 Harry Hines Boulevard Dallas TX 75390-9038 USA;</p> <p>Department of BiochemistryThe University of Texas Southwestern Medical Center5323 Harry Hines Boulevard Dallas TX 75390-9038 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cross-coupling&option=203" rel="nofollow">cross-coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=heterocycles&option=203" rel="nofollow">heterocycles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sulfur&option=203" rel="nofollow">sulfur;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sulfurane&option=203" rel="nofollow">sulfurane;</a> </p> <div class="translation"> 机译：交叉偶联;杂环;硫;硫砜; 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