Unique Oil-in-Brine Pickering Emulsion Using Responsive Antipolyelectrolyte Functionalized Latex: A Versatile Emulsion Stabilizer

摘要

A simple and straightforward approach to synthesize oil-in-water (O/W) emulsions under high salinity and temperature using zwitterion-functionalized latexes are presented in this work. First, well-defined functionalized latexes were synthesized by emulsifier-free emulsion copolymerization in the presence of precursor sulfobetaine comonomer using brine as a continuous phase. The surface-functionalized latex particles were then characterized by DLS, SEM, TEM, XPS, and TGA. The functionalized latex exhibited antipolyelectrolyte behavior in high salinity brine and at high temperatures. The effects of salinity, temperature, and pH on the long-term stability of the particles were investigated. Further, to evaluate the potential in high salinity brine and high temperature, the saltphilic functionalized latexes were utilized to stabilize the oil/brine (O/W) interface without any other additives. The latex enabled the formation of a stable Pickering emulsion system with low solid content (<0.02% w/w) in the presence of 50% v/v n-decane. The functionalized latexes were self-assembled at the O/W interface as a spherical colloidosome in high salinity brine through hydrophobic interactions and irreversible adsorption. The supraparticles were imaged with SEM, providing an insight that the exterior of the emulsion droplets is stabilized by the saltphilic latex particles, forming a protective layer at the oil-water interface through electrostatic repulsion. The antipolyelectrolyte latex can be utilized as a novel emulsion stabilizer, which can provide a versatile alternative for applications in a complex environment such as high salinity, temperature, and low or high pH.