Electrochemical deposition of highly loaded polypyrrole on individual carbon nanotubes in carbon nanotube film for supercapacitor

摘要

In this work, a core-shell structured pseudocapacitive anode is fabricated through electrochemical deposition of highly loaded (3.89 mg cm(-2)) polypyrrole (PPy) on individual carbon tubes in electrochemically pretreated carbon nanotube film (ECNT) to afford ECNT/PPy electrode. The core-shell structure significantly promotes the charge transfer for energy storage reaction and buffers the volume change of PPy during charge/discharge cycles, leading to much improved pseudocapacitive behaviors for ECNT/PPy. It can retain 75.2% of its capacitance (965.3 mF cm(-2) at 1 mA cm(-2)) when the discharge current increased 40 times to 40 mA cm(-2). After 10,000 galvanostatic charge/discharge cycles, ECNT/PPy can maintain 89.1% of its initial capacitance. The asymmetric supercapacitor (ASC) assembled by using ECNT/PPy and CNT/MnO2 as anode and cathode, respectively demonstrate a high volumetric energy density of 3.63 mWh cm(-3) at the power density of 13.86 mWcm(-3). After 10,000 galvanostatic charge/discharge cycles, the ASC can retain 89.0% of its capacitance, showing its good cyclic stability.