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Ionoluminescence studies of combustion synthesized Dy~(3+) doped nano crystalline forsterite

机译:燃烧合成的Dy〜(3+)掺杂纳米晶镁橄榄石的电致发光研究

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摘要

Ionoluminescence (IL) of nano crystalline Mg_2SiO_4:Dy~(3+) pellet samples bombarded with 100 MeV Si~(+8) ions with fluences in the range (1.124e22.480) × 10~(12) ions cm~(-2) have been studied. Two prominent IL bands with peaks at w480 nm and w580 nm and a weak band with peak at w670 nm are recorded. The characteristic peaks are attributed to luminescence center activated by Dy~(3+) ions due to the transitions ~4F_9/2→~6H_(15/2), ~6H_(13/2) and ~6H_(11/2). It is found that IL intensity initially decreases rapidly and then continuous to decrease slowly with further increase in ion fluence. The reduction in the Ionoluminescence intensity with increase of ion fluence might be attributed to degradation of SieO (2n_3) bonds present on th surface of the sample and/or due to lattice disorder produced by dense electronic excitation unde heavy ion irradiation.
机译:纳米晶体Mg_2SiO_4:Dy〜(3+)团粒样品的电致发光(IL)被100 MeV Si〜(+8)离子轰击,能量密度在(1.124e22.480)×10〜(12)离子cm〜(- 2)已经研究过。记录了两个突出的IL谱带,其峰分别在w480 nm和w580 nm处,以及一个弱谱带,其峰在w670 nm处。由于〜4F_9 / 2→〜6H_(15/2),〜6H_(13/2)和〜6H_(11/2)的跃迁,特征峰归因于Dy〜(3+)离子激活的发光中心。已经发现,随着离子通量的进一步增加,IL强度开始迅速下降,然后持续缓慢下降。随着离子通量的增加,电离发光强度的降低可能归因于样品表面上存在的SieO(2n_3)键的降解和/或由于重离子辐照引起的密集电子激发产生的晶格紊乱。

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