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Numerical simulation on crystallization-induced warpage of injection-molded PP/EPDM part

机译:结晶诱导的注塑型PP / EPDM部分翘曲的数值模拟

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摘要

Prediction on crystallization-induced warpage in injection-molded semi-crystalline polymers is important in satisfying the required specifications of molded products. In this study, we chose a polypropylene (PP)/ethylene propylene diene monomer (EPDM) blend as the model system, and use Autodesk's Moldflow Insight to simulate the crystallization behavior and the influence on the warpage of the injection-molded box-shaped PP/EPDM sample. The required crystallization parameters of the PP/EPDM were taken from differential scanning calorimetry (DSC) and experimentally estimated on a similar PP in the Moldflow material library. The FWO, Jeziorny, and Coats-Redfern methods were applied to describe the crystallization kinetics and estimate the required crystallization parameters. The simulation on warpage was then conducted with and without the crystallization. When the crystallization is considered, the warpage of the box-shaped PP/EPDM increased more significantly than that for the PP, which can be attributed to the more uneven crystallization resulting from slower crystallization kinetics of the PP/EPDM. With a 10 degrees C increase in the coolant temperature, which reduced temperature gradient in the sample, a spatially more homogeneous crystallization can be achieved. Consequently, the side edge warpage of the injection-molded box-shaped PP/EPDM decreased considerably.
机译:结晶诱导的注塑半结晶聚合物中的结晶型翘曲的预测对于满足所需的模塑产品规格是重要的。在这项研究中,我们选择了聚丙烯(PP)/乙烯二烯单体(EPDM)混合作为模型系统,并使用Autodesk的模型洞察力来模拟结晶行为和对注塑盒形PP翘曲的影响/ EPDM样本。 PP / EPDM的所需结晶参数取自差示扫描量热法(DSC),并在模型材料文库中进行了在类似的PP上进行实验估计。应用FWO,Jeziorny和涂层方法来描述结晶动力学并估计所需的结晶参数。然后用和没有结晶进行翘曲的模拟。当考虑结晶时,箱形PP / EPDM的翘曲比PP更显着增加,这可能归因于PP / EPDM的较慢的结晶动力学产生的更不均匀的结晶。在冷却剂温度下增加10摄氏度,降低样品中的温度梯度,可以实现空间更均匀的结晶。因此,注塑成型箱形PP / EPDM的侧边缘翘曲显着降低。

著录项

  • 来源
    《Journal of Polymer Research 》 |2019年第9期| 共11页
  • 作者单位

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

    DSM Mat Sci Ctr Dept Proc &

    Properties Urmonderbaan 22 NL-6167 RD Geleen Netherlands;

    Univ Shanghai Sci &

    Technol Sch Mat Sci &

    Technol Shanghai 200093 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学 ;
  • 关键词

    Warpage; Injection-molded semi-crystalline polymer; Crystallization kinetics; Simulation; PP; EPDM;

    机译:翘曲;注塑模拟半晶聚合物;结晶动力学;模拟;PP;EPDM;

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