How do polymer molecular weights influence the luminescence properties of metal-containing polymers? A case study of platinum(II) complex end-functionalized polymers

He Qun; Wang Chen; Xiao Jie; Wang Yongyue; Zhou Yufeng; Zheng Nan; Zhang Bin; Bu Weifeng

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How do polymer molecular weights influence the luminescence properties of metal-containing polymers? A case study of platinum(II) complex end-functionalized polymers

机译：聚合物分子量如何影响含金属聚合物的发光性质？铂（II）复合末端官能化聚合物的案例研究

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Poly (ethylene glycol)s (PEGs) terminated with platinum(ii) complexes show dramatically blue-shifted emission bands and sharply increased luminescence quantum yields with increasing molecular weights of PEGs. Such dramatic changes stem from the structural transitions from lamellar to disordered, and sharply reduced pi-pi stacking interactions between the platinum(ii) complexes.

机译：用铂（II）络合物终止的聚（乙二醇）S（PEG）显着地显示出蓝移发带状，并随着厚度的分子量急剧增加发光量子产率。这种显着的变化源于层层的结构转变，使铂（II）复合物之间的PI-PI堆叠相互作用急剧降低。

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《Journal of Materials Chemistry, C. materials for optical and electronic devices》 |2018年第45期|共5页
作者
He Qun; Wang Chen; Xiao Jie; Wang Yongyue; Zhou Yufeng; Zheng Nan; Zhang Bin; Bu Weifeng;
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作者单位

Lanzhou Univ Key Lab Nonferrous Met Chem &

Resources Utilizat State Key Lab Appl Organ Chem Lanzhou 730000 Gansu Peoples R China;

Lanzhou Univ Key Lab Nonferrous Met Chem &

Resources Utilizat State Key Lab Appl Organ Chem Lanzhou 730000 Gansu Peoples R China;

Lanzhou Univ Key Lab Nonferrous Met Chem &

Resources Utilizat State Key Lab Appl Organ Chem Lanzhou 730000 Gansu Peoples R China;

Lanzhou Univ Key Lab Nonferrous Met Chem &

Resources Utilizat State Key Lab Appl Organ Chem Lanzhou 730000 Gansu Peoples R China;

Zhengzhou Univ Sch Mat Sci Engn Zhengzhou 450002 Henan Peoples R China;

South China Univ Technol State Key Lab Luminescent Mat &

Devices Guangzhou 510640 Guangdong Peoples R China;

Zhengzhou Univ Sch Mat Sci Engn Zhengzhou 450002 Henan Peoples R China;

Lanzhou Univ Key Lab Nonferrous Met Chem &

Resources Utilizat State Key Lab Appl Organ Chem Lanzhou 730000 Gansu Peoples R China;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. How do polymer molecular weights influence the luminescence properties of metal-containing polymers? A case study of platinum(II) complex end-functionalized polymers [J] . He Qun, Wang Chen, Xiao Jie, Journal of Materials Chemistry, C. materials for optical and electronic devices . 2018,第45期

机译：聚合物分子量如何影响含金属聚合物的发光性质？铂（II）复合末端官能化聚合物的案例研究
2. Modifying polysulfone into a bidentate Schiff base type macromolecular ligand and study on photoluminescence property of polymer-rare earth complexes of Eu(III) and Tb(III) [J] . Zhang Dandan, Gao Baojiao, Cui Kunli Journal of Polymer Research . 2016,第12期

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3. From metal complexes to metallosupramolecular polymers via polycondensation: Synthesis, structure and electrochromic properties of Co(III)- and Fe(III)-based metallosupramolecular polymers with aromatic azo ligands [J] . Bandyopadhyay A., Higuchi M. European Polymer Journal . 2013,第6期

机译：通过缩聚反应从金属配合物到金属超分子聚合物：具有芳族偶氮配体的Co（III）和Fe（III）基金属超分子聚合物的合成，结构和电致变色性能
4. Luminescence Properties of Organometallic/Coordination Oligomers and Polymers Containing Diphosphine and Diisocyanide Assembling Ligands: Comparison between Mononuclear Model Complexes and Polymers [C] . Pierre D. Harvey Macromolecular Symposia 209; Organometallic and Coordination Clusters and Polymers: Syntheses and Applications Symposium; 20040529-0601; London(CA) . 2004

机译：有机金属/配位低聚物和含二膦和二异氰酸酯组装配体的聚合物的发光性质：单核模型配合物和聚合物之间的比较。
5. Processing-structure-property studies of: (I) submicron polymeric fibers produced by electrospinning and (II) films of linear low density polyethylenes as influenced by the short chain branch length in copolymers of ethylene/1-butene, ethylene/1-hexene and ethylene/1-octene synthesized by a single site metallocene catalyst. [D] . Gupta, Pankaj. 2004

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6. On the Influence of Crosslinker on Template Complexation in Molecularly Imprinted Polymers: A Computational Study of Prepolymerization Mixture Events with Correlations to Template-Polymer Recognition Behavior and NMR Spectroscopic Studies [O] . Siamak Shoravi, Gustaf D. Olsson, Björn C. G. Karlsson, 2014

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How do polymer molecular weights influence the luminescence properties of metal-containing polymers? A case study of platinum(II) complex end-functionalized polymers

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