New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials

摘要

the application relates to new systems fotoinicjujących to fotoinicjowanej cation polymerization processes, rodnikowej, tiol - en and hybrid, the new complex compounds terbu (iii)method of manufacturing them, uses complex compounds terbu (iii)new luminescencyjnych molecular probes to monitor polymerization processes and new materials research luminescencyjnych molecular sensor for coating.new systems fotoinicjujące to fotoinicjowanej cation polymerization processes, rodnikowej, tiol - en and hybrid containing salts oniowe and ko - initiator, characterized by that,that contain (a) at least one salt selected from among the following: oniową jodoniowe salts selected from heksafluorofosforanu difenylojodoniowego, heksafluoroantymonianu difenylojodoniowego,heksafluorofosforanu 4 - methyl - 4 '- izopropylodifenylojodoniowego, heksafluorofosforanu 4,4' - dimetylodifenylojodoniowego,tetrakis pentafluorofenyloboranu 4 - methyl - 4 '- izopropylodifenylojodoniowego; salts sulfoniowe selected from heksafluorofosforanu trifenylo - sulfoniowego and heksafluoroantymonianu trifenylosulfoniowego;and (b) at least one selected from the group of ko - initiator complex compounds terbu (iii) of general formula (1), in which: a1 means the grouping of general formula (2),in which the substituent r1 means a hydrogen atom or fluorine atom substituent; r2 means hydrogen atom, chlorine atom, methyl group, the group trifluorometylową; substituent r3 is hydrogen atom, bromine atom,methyl substituent group; r4 represents hydrogen atom, fluorine atom, metoksylową group; a2 means the grouping of general formula (3),in which the substituent group or butyl group oktylową r5 means; or a2 means group of the formula (4), x is 0, 1 or 2; n is the number of total from 0 to 7.