Equations of State and Anisotropy of Fe‐Ni‐Si Alloys

机译：Fe-Ni-Si合金的状态方程和各向异性

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Abstract > We present powder X‐ray diffraction data on body centered cubic (bcc)‐ and hexagonal close packed (hcp)‐structured Fe <sub>0.91</sub> Ni <sub>0.09</sub> and Fe <sub>0.8</sub> Ni <sub>0.1</sub> Si <sub>0.1</sub> at 300?K up to 167 and 175?GPa, respectively. The alloys were loaded with tungsten powder as a pressure calibrant and helium as a pressure transmitting medium into diamond anvil cells, and their equations of state and axial ratios were measured with high statistical quality. These equations of state are combined with thermal parameters from previous reports to improve the extrapolation of the density, adiabatic bulk modulus, and bulk sound speed to the pressures and temperatures of Earth's inner core. We propagate uncertainties and place constraints on the composition of Earth's inner core by combining these results with available data on light‐element alloys of iron and seismic observations. For example, the addition of 4.3 to 5.3?wt% silicon to Fe <sub>0.95</sub> Ni <sub>0.05</sub> alone can explain geophysical observations of the inner core boundary, as can up to 7.5?wt% sulfur with negligible amounts of silicon and oxygen. Our findings favor an inner core with less than ～2 wt% oxygen and less than 1 wt% carbon, although uncertainties in electronic and anharmonic contributions to the equations of state may shift these values. The compositional space widens toward the center of the Earth, considering inner core seismic gradients. We demonstrate that hcp‐Fe <sub>0.91</sub> Ni <sub>0.09</sub> and hcp‐Fe <sub>0.8</sub> Ni <sub>0.1</sub> Si <sub>0.1</sub> have measurably greater c / </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”XML：ID =“JGRB52776-ABS-ABS-ABS-0001”> <标题类型=“main”>抽象</标题> >我们呈现粉末X射线衍射数据在身体中心立方（BCC） - 和六边形关闭填充（HCP） - 结构化Fe <sub> 0.91 </ sub> Ni <sub> 0.09 </ sub>和Fe <sub> 0.8 </ sub> ni <sub> 0.1 </ sub> Si <sub> 0.1 </ sub>以300Ωk，分别为167和175？GPA。将合金用钨粉作为压力校准物和氦作为压力传递介质加载到金刚石砧座中，并以高统计质量测量它们的状态和轴向比的方程。这些状态方程与先前报告的热参数相结合，以改善密度，绝热模量和散装速度的外推到地球内核的压力和温度。通过将这些结果与铁和地震观测的轻质合金的可用数据相结合，我们宣传不确定性并将其限制在地球内核的组成上。例如，单独添加4.3至5.3〜5.3〜5.3〜5.3〜5.3wt <sub> 0.95 <sub> 0.05 </ sub>可以解释内核边界的地球物理观察，可以高达7.5？wt硅和氧气量可忽略不计的硫。我们的研究结果有利于氧气小于约2wt％的内核，碳少于1％的碳，尽管电子和厌氧贡献对国家方程的不确定性可能会转变这些值。考虑内核地震梯度，构图空间朝向地球的中心变宽。我们证明HCP-FE <sub> 0.91 </ sub> Ni <sub> 0.09 </ sub> 0.8 </ sub> ni <sub> 0.1 </ sub> si <sub> 0.1 < / sub>具有可测量的更大 c </ i> / </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-34677/'>《Journal of geophysical research. Solid earth: JGR》</a> <b style="margin: 0 2px;">|</b><span>2018年第6期</span><b style="margin: 0 2px;">|</b><span>共29页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Morrison Rachel A.&option=202" target="_blank" rel="nofollow">Morrison Rachel A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jackson Jennifer M.&option=202" target="_blank" rel="nofollow">Jackson Jennifer M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sturhahn Wolfgang&option=202" target="_blank" rel="nofollow">Sturhahn Wolfgang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Dongzhou&option=202" target="_blank" rel="nofollow">Zhang Dongzhou;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Greenberg Eran&option=202" target="_blank" rel="nofollow">Greenberg Eran;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Seismological LaboratoryCalifornia Institute of TechnologyPasadena CA USA;</p> <p>Seismological LaboratoryCalifornia Institute of TechnologyPasadena CA USA;</p> <p>Seismological LaboratoryCalifornia Institute of TechnologyPasadena CA USA;</p> <p>Hawaii Institute of Geophysics and PlanetologyUniversity of Hawaii at ManoaHonolulu HI USA;</p> <p>Center for Advanced Radiation SourcesUniversity of ChicagoChicago IL USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/163.html" title="地球物理学">地球物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fe alloys&option=203" rel="nofollow">Fe alloys;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Earth's core&option=203" rel="nofollow">Earth's core;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=high pressure&option=203" rel="nofollow">high pressure;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=X‐ray diffraction&option=203" rel="nofollow">X‐ray diffraction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=equation of state&option=203" rel="nofollow">equation of state;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=elastic anisotropy&option=203" rel="nofollow">elastic anisotropy;</a> </p> <div class="translation"> 机译：Fe合金;地球的核心;高压;X射线衍射;状态方程;弹性各向异性; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025592315.html">Equations of State and Anisotropy of Fe‐Ni‐Si Alloys</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Morrison Rachel A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Morrison Rachel A.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jackson Jennifer M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jackson Jennifer M.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sturhahn Wolfgang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sturhahn Wolfgang,</a> <a href="/journal-foreign-34677/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of geophysical research. 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class="tuijian_auth tuijian_authcolor">,童权</a> <span> <a href="/journal-cn-7415/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 重庆理工大学学报（自然科学版） </a> </span> <span> . 2021</span><span>,第007期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201295158747.html">合金元素对HDDR工艺Nd-Fe-B合金粉显微组织和磁各向异性的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高建荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 高建荣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋晓平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋晓平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王笑天&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王笑天</a> <span> <a href="/journal-cn-57221/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国稀土学报 </a> </span> <span> . 1997</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-39434_thesis/020222417627.html">CaO-CaF2渣对Fe-Ni-Si合金还原脱磷的反应机理研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张国华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张国华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈佩仙&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈佩仙</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=储少军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,储少军</a> <span> <a href="/conference-cn-39434/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第24届全国铁合金学术研讨会 </a> <span> <span> . 2016</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315559659.html">地核环境下铁硅合金状态方程研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=齐少鹏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 齐少鹏</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120208205902.html">利用理想气体状态方程间接测定铝硅合金铝含量的装置</a> <b>[P]</b> . <span> 中国专利： CN208206716U </span> <span> . 2018.12.07</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061202342473.html">R‑T‑B系合金粉末、各向异性粘结磁体用复合物和各向异性粘结磁体</a> <b>[P]</b> . <span> 中国专利： CN103907163B </span> <span> . 2017.02.15</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130418969406.html">SILICON WAFER ON WHICH Ni AND Ni ALLOY FILM IS FORMED, FORMING METHOD OF Ni AND Ni ALLOY FILM ON Si WAFER, SURFACE ROUGHENING PROCESSING LIQUID TO SURFACE OF Si WAFER IN FORMING Ni AND Ni ALLOY FILM, AND SURFACE ROUGHENING PROCESSING METHOD OF THE SURFACE</a> <b>[P]</b> . <span> 外国专利：  JP2014181373A </span> <span> . 2014-09-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：形成Ni和Ni合金膜的硅晶片，在Si晶片上形成Ni和Ni合金膜的方法，在形成Ni和Ni合金膜的硅晶片表面上进行表面粗加工的液体，以及在表面上进行表面粗加工的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130413146020.html">A method of forming a Ni and Ni alloy film on a Si wafer, a method of forming a Ni and Ni alloy film on a Si wafer, a surface roughening treatment liquid of the surface of the Si wafer at the time of forming the Ni and Ni alloy film, Method of conversion treatment</a> <b>[P]</b> . <span> 外国专利：  JP5996463B2 </span> <span> . 2016-09-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在Si晶片上形成Ni和Ni合金膜的方法，在Si晶片上形成Ni和Ni合金膜的方法，在形成Ni时Si晶片的表面的表面粗糙化处理液和镍合金膜，转化处理方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130440890827.html">METHOD FOR SPECIFYING SIZE OF MAXIMUM NONMETAL INCLUSION IN SLAB STAGE OF Fe-Ni ALLOY PLATE AND Fe-Ni ALLOY PLATE SPECIFIED IN SIZE OF MAXIMUM NONMETAL INCLUSION IN Fe-Ni ALLOY SLAB</a> <b>[P]</b> . <span> 外国专利：  JP2005274401A </span> <span> . 2005-10-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Fe-Ni合金板的最大非金属夹杂物的板坯尺寸确定方法和Fe-Ni合金板的最大非金属夹杂物的特定板尺寸确定方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 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