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Partial replacement of urea-formaldehyde adhesive with fungal biomass and soy flour in plywood fabrication

机译:用真菌生物量和大豆面粉在胶合板制造中部分替代尿素 - 甲醛粘合剂

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摘要

The aim of this study was to evaluate the partial substitution of urea-formaldehyde (UF) adhesive by fungal biomass (FB) and soy flour (SF) for plywood (PW) fabrication. For this purpose, three substitute rates of 5%, 10%, and 15% based on the dry weight of UF were examined. The physical properties, functional groups, and thermo-stability of the adhesives were characterized as well as three-ply PW panels bonded with the adhesives were evaluated in terms of water absorption (WA), thickness swelling (TS), dry and wet shear strength, and formaldehyde emission (FE). The results show that FB and SF lead in higher viscosity and longer gel time than UF adhesive. The UF and UF modified with FB and SF showed similar Fourier-transform infrared spectroscopy (FT-IR) spectral patterns. In addition, fully cured FB-containing UF adhesive possessed higher thermal stability compared to UF and UF + SF adhesives. The results revealed that the partial replacement of UF adhesive with FB and SF has no significant negative effect on the dimensional stability of PW panels. The partial replacement of UF adhesive with FB and SF, particularly in substitute rate of 10% and 15%, did significantly reduce the FE while not significantly influencing the shear strength under both dry and wet conditions. Eventually, the FB-containing UF adhesive presented similar good performance and lower FE compared with UF and UF + SF adhesives. Hence, FB can be a promising natural raw material to use in wood adhesives with acceptable performance.
机译:本研究的目的是评估通过真菌生物量(FB)和大豆面粉(PW)制备的尿素生物量(FB)和大豆面粉(PW)制备的尿素 - 甲醛(UF)粘合剂的部分取代。为此目的,研究了基于UF的干重的三种替代率为5%,10%和15%。粘合剂的物理性质,官能团和热稳定性,以及与粘合剂结合的三层PW板在吸水率(WA),厚度溶胀(TS),干燥和湿剪强度方面进行了评价,和甲醛排放(Fe)。结果表明,FB和SF在比UF粘合剂更高的粘度和较长的凝胶时间内。用FB和SF修改的UF和UF显示出类似的傅里叶变换红外光谱(FT-IR)光谱图案。此外,与UF和UF + SF粘合剂相比,含有全固化的FB的UF粘合剂具有更高的热稳定性。结果表明,具有FB和SF的UF粘合剂的部分替代对PW板的尺寸稳定性没有显着的负面影响。使用FB和SF的UF粘合剂的部分替代,特别是替代率为10%和15%,确实显着降低了FE的,而在干燥和潮湿条件下不会显着影响剪切强度。最终,与UF和UF + SF粘合剂相比,含FB的UF粘合剂呈现出类似的良好性能和低级。因此,FB可以是具有可接受性能的木材粘合剂的有希望的天然原料。

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