Structure and Dynamics of Complex Ions in YbCl3-MCl (M = K, Cs) Melts Based on Raman Spectroscopy Data

Zakiryanova I. D.

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Structure and Dynamics of Complex Ions in YbCl3-MCl (M = K, Cs) Melts Based on Raman Spectroscopy Data

机译：基于拉曼光谱数据的YbCl3-MCL（M = K，CS）熔融的复合离子的结构和动力学

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Structural information on high-temperature ionic melts YbCl3-MCl (M = K, Cs) was generated in situ using Raman spectroscopy. Force constants of Yb-Cl bonds and orientational relaxation times of YbCl63- complex ions were calculated. Empirical equations describing the correlation between YbCl63- dynamic behavior and the conductivity of the studied melts were obtained.

机译：使用拉曼光谱法原位产生关于高温离子熔化YbCl 3-MCL（M = K，CS）的结构信息。计算YB-Cl键的力常数和YbCl63-复合离子的取向弛豫时间。获得了描述YBCL63-动力学行为与所研究熔体的电导率之间的相关性的经验方程。

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来源
《Journal of Applied Spectroscopy》 |2019年第3期|共6页
作者
Zakiryanova I. D.;
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作者单位

Russian Acad Sci Ural Branch Inst High Temp Electrochem 22 S Kovalevskaya Str Ekaterinburg 620219 Russia;

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原文格式 PDF
正文语种 eng
中图分类光学;
关键词
Raman spectroscopy; YbCl3; alkali-metal chlorides; melt; structure; relaxation time; electrical conductivity;

机译：拉曼光谱;YBCL3;碱金属氯化物;熔体;结构;放松时间;电导率;

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1. Structure and Dynamics of Complex Ions in YbCl3-MCl (M = K, Cs) Melts Based on Raman Spectroscopy Data [J] . Zakiryanova I. D. Journal of Applied Spectroscopy . 2019,第3期

机译：基于拉曼光谱数据的YbCl3-MCL（M = K，CS）熔融的复合离子的结构和动力学
2. CORRELATION BETWEEN HYDROXIDE ION DYNAMICS AND TRANSPORT PROPERTIES OF HYDROXIDE/CHLORIDE MELTS ACCORDING TO RAMAN SPECTROSCOPY DATA [J] . I. D. Zakiryanova Journal of Applied Spectroscopy . 2014,第2期

机译：根据拉曼光谱数据，氢氧根离子动力学与氢氧根/氯离子熔体的传输性质之间的相关性
3. Structure of Cs2O-B2O3 Glass and Melts: The Raman Spectroscopy Data [J] . A. A. Osipov, L. M. Osipova Glass Physics and Chemistry: A Journal on the Structural, Physical, and Chemical Properties and Nature of Inorganic Glasses and Glass-Forming Melts . 2014,第4期

机译：Cs2O-B2O3玻璃和熔体的结构：拉曼光谱数据
4. Analysis of poly-(dA)-poly(dT) structure by Raman spectroscopy and lattice dynamics [C] . Yao-Yong Meng, South China Normal Univ., Guangzhou, 1999 International Conference on Biomedical Optics . 1999

机译：用拉曼光谱和晶格动力学分析聚（dA）-聚（dT）结构
5. Diffractive-optics-based fifth-order Raman spectroscopy of ultrafast liquid dynamics. [D] . Milne, Christopher Jackson. 2002

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6. Structure and dynamics of the DNA-binding protein HU of B. stearothermophilus investigated by Raman and ultraviolet-resonance Raman spectroscopy [O] . Doinita Serban, Sandra F. Arcineigas, Constantinos E. Vorgias, 2003

机译：拉曼和紫外共振拉曼光谱研究嗜热脂肪芽孢杆菌DNA结合蛋白HU的结构和动力学
7. Structure and dynamics of the DNA-binding protein HU of B. stearothermophilus investigated by Raman and ultraviolet-resonance Raman spectroscopy3 [O] . Serban, Doinita, Arcineigas, Sandra F., Vorgias, Constantinos E., 2003

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Structure and Dynamics of Complex Ions in YbCl3-MCl (M = K, Cs) Melts Based on Raman Spectroscopy Data

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