CORRELATION BETWEEN HYDROXIDE ION DYNAMICS AND TRANSPORT PROPERTIES OF HYDROXIDE/CHLORIDE MELTS ACCORDING TO RAMAN SPECTROSCOPY DATA

摘要

Using data obtained in analysis of the band contour for the totally symmetric stretching vibration of the OH~- anion in Raman spectra of hydroxide/chloride ionic melts, a correlation has been established between the orientational relaxation time and effective moment of inertia of the hydroxide ion and the transport properties of the electrolyte.