Thermodynamics and Kinetics of Curing Reaction Between Azide Binder ATP and Bispropargyl Succinate

Li Na; Zhao Fengqi; An Ting; Yang Yanjing; Li Hui; Zhang Jiankan; Zhang Ming

摘要

Abstract > The thermodynamics and kinetics of the curing reactions between azide binder ATP and bispropargyl succinate (BPS) were studied by using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (i.?e., the activation enthalpies, the activation entropies, the activation free energies), the rate constant, three kinetic parameters (i.?e., the activation energies, the pre‐exponential constant and the reaction order) and the enthalpies of the curing reactions between ATP and BPS in the temperature range of 323.15–338.15?K were obtained, showing that the main reaction leading to a triazole structure easily took place in the studied temperature. The linear relationship between ln k and the molar ratio of triple bonds to azide groups was found. Furthermore, the corresponding kinetic equation describing the curing reaction between ATP and BPS was dα/dt=10 ?4.12 (1‐α) 1.01 at 333.15?K. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 通过使用微量微量计研究叠氮化物粘合剂ATP和双丙基琥珀酸盐（BPS）之间的热力学和动力学。在实验性和计算结果的基础上，三个热力学参数（I.?E。，激活焓，激活熵，激活自由能），速率常数，三个动力学参数（I.IE。，激活能量），获得预指数常数和反应顺序），得到了在323.15-338.15μl≤k的温度范围内的ATP和BPS之间的固化反应的焓，显示出导致三唑结构的主要反应容易发生研究温度。 LN之间的线性关系 k </ i> 发现了三键与叠氮基组的摩尔比。此外，描述ATP和BPS之间的固化反应的相应动力学方程是Dα/ DT = 10 ？4.12 </ sup> （1-α） 1.01 </ sup> 在333.15？k。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2020年第6期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Na&option=202" target="_blank" rel="nofollow">Li Na;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Fengqi&option=202" target="_blank" rel="nofollow">Zhao Fengqi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=An Ting&option=202" target="_blank" rel="nofollow">An Ting;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Yanjing&option=202" target="_blank" rel="nofollow">Yang Yanjing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Hui&option=202" target="_blank" rel="nofollow">Li Hui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Jiankan&option=202" target="_blank" rel="nofollow">Zhang Jiankan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Ming&option=202" target="_blank" rel="nofollow">Zhang Ming;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> <p>National Key Lab of Science and Technology on Propellant and Explosion CombustionXi'an Modern Chemistry Research InstituteXi'an 710065 P.R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Azide binder ATP&option=203" rel="nofollow">Azide binder ATP;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bispropargyl succinate (BPS)&option=203" rel="nofollow">Bispropargyl succinate (BPS);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Curing&option=203" rel="nofollow">Curing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Microcalorimeter&option=203" rel="nofollow">Microcalorimeter;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thermodynamics&option=203" rel="nofollow">Thermodynamics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kinetics&option=203" rel="nofollow">Kinetics;</a> </p> <div class="translation"> 机译：叠氮化物粘合剂ATP;双丙烷琥珀酸酯（BPS）;固化;微量微量计;热力学;动力学; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" 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class="tuijian_auth tuijian_authcolor">,李翠林</a> <span> <a href="/journal-cn-12032/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学研究与应用 </a> </span> <span> . 2017</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-31972_thesis/02022479576.html">双取代苯并-15-冠-5的合成及其与轻稀土硝酸盐配位作用的热力学性质</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张衡益&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张衡益</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=白小鹏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,白小鹏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘育&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘育</a> <span> <a href="/conference-cn-31972/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 全国第十届大环化学、第二届超分子化学学术讨论会 </a> <span> <span> . 2000</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312984947.html">钛酸盐离子交换过程动力学和热力学研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=魏涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 魏涛</a> <span> . 2002</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120681319.html">晶型转变了的(S)-(3-吡啶羧基酰胺,6-[4-[2-[[3-(9H-咔唑-4-基氧基)-2-羟丙基]氨基]-2-甲丙基]苯氧基]-半琥珀酸盐水合物</a> <b>[P]</b> . <span> 中国专利： CN1989129B </span> <span> . 2010.11.10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105194000.html">晶型转变了的(S)－(3－吡啶羧基酰胺，6－4－2－3－(9H－咔唑－4－基氧基)－2－羟丙基氨基－2－甲丙基苯氧基－半琥珀酸盐水合物</a> <b>[P]</b> . <span> 中国专利： CN1989129A </span> <span> . 2007-06-27</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130441453555.html">Process for balancing a continuous polymerization reaction and/or predicting the molecular mass distribution of the product of the reaction in one or more connected reactors comprises coupling the kinetic and thermodynamic models formed</a> <b>[P]</b> . <span> 外国专利：  DE10227270A1 </span> <span> . 2004-01-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在一个或多个连接的反应器中平衡连续聚合反应和/或预测反应产物的分子量分布的方法包括偶联形成的动力学模型和热力学模型 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130431680451.html">Computer-aided simulation of chemical or biochemical reaction kinetics, involves specifying one or multiple molecular reactions of reaction kinetics by molecule types, reaction types and interaction constant, involved in molecular reaction</a> <b>[P]</b> . <span> 外国专利：  DE102007004624A1 </span> <span> . 2008-07-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：计算机辅助的化学或生化反应动力学模拟，涉及通过分子类型，反应类型和相互作用常数（涉及分子反应）指定反应动力学的一个或多个分子反应 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130500978948.html">Cu(I)-catalyzed azide-alkyne cycloadditions (CuAAC) ligands and methods for carrying out Cu(I)-catalyzed azide-alkyne cycloaddition reactions</a> <b>[P]</b> . <span> 外国专利：  US11167277B2 </span> <span> . 2021-11-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Cu（i） - 催化叠氮化物 - 炔烃环加成（Cuaac）配体和用于进行Cu（I）的方法 - 催化叠氮化物 - 炔环加油反应 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul 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