3D printing hybrid organometallic polymer‐based biomaterials via laser two‐photon polymerization

Bal?iūnas Evaldas; Baldock Sara J; Drei?? Nade?da; Grubliauskait? Monika; Coultas Sarah; Rochester David L; Valius Mindaugas; Hardy John G; Baltriukien? Daiva

摘要

Abstract > Materials with microscale structures are gaining increasing interest due to their range of technical and medical applications. Additive manufacturing approaches to such objects via laser two‐photon polymerization, also known as multiphoton fabrication, enable the creation of new materials with diverse and tunable properties. Here, we investigate the properties of 3D structures composed of organometallic polymers incorporating aluminium, titanium, vanadium and zirconium. The organometallic polymer‐based materials were analysed using a variety of techniques including SEM, energy‐dispersive X‐ray spectroscopy, X‐ray photoelectron spectroscopy analysis and contact angle measurements and their biocompatibility was tested in vitro . Cell viability and mode of death were determined by 3‐(4,5‐dimethyl‐2‐thiazolyl)‐2,5‐diphenyl‐2H‐tetrazolium bromide (MTT) assay and acridine orange/ethidium bromide staining. Polymers incorporating Al, Ti and Zr supported cell adhesion and proliferation, and showed low toxicity in vitro , whereas the organometallic polymer incorporating V was shown to be cytotoxic. Inductively coupled plasma optical emission spectrometry suggested that leaching of the V from the organometallic polymer is the likely cause of this. The preparation of the organometallic polymers is straightforward and both simple 2D and complex 3D structures can be fabricated with ease. Resolution tests of the newly developed organometallic polymer incorporating Al show that suspended lines with widths down to 200?nm can be fabricated. We believe that the materials described in this work show promising properties for the development of objects with sub‐micron features for biomedical applications (e.g. biosensors, drug delivery devices, tissue scaffolds etc.). ? 2019 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 由于其技术和医疗应用的系列，具有微观结构的材料正在增加利益。通过激光双光子聚合对这些物体的添加剂制造方法，也称为多光子制造，使得具有多样化和可调性的新材料。在这里，我们研究了由含铝，钛，钒和锆的有机金属聚合物组成的3D结构的性质。使用各种技术分析了有机金属聚合物基材料，包括SEM，能量分散X射线光谱，X射线光电子能谱分析和接触角测量以及它们的生物相容性进行了测试在体外</ i> 。通过3-（4,5-二甲基-2-噻唑基）-2,5-二苯基-2H-四唑溴铵（MTT）测定和吖啶橙/溴化乙烷染色来测定细胞活力和死亡方式。掺入Al，Ti和Zr的聚合物支持的细胞粘附和增殖，并显示出低毒性在体外</ i> ，而有机金属聚合物掺入V的载体是细胞毒性的。电感耦合等离子体光学发射光谱表明，来自有机金属聚合物的V的浸出是可能的原因。有机金属聚合物的制备是简单的，并且可以轻松地制造简单的2D和复杂的3D结构。包含A1的新开发的有机金属聚合物的分辨率测试显示，可以制造宽度为200μm的悬浮线。我们认为这项工作中描述的材料表明了具有用于生物医学应用的子微米特征的物体的有希望的性质（例如，生物传感器，药物输送装置，组织支架等）。还2019年作者。聚合物国际</ i> John Wiley＆amp出版; SONS LTD代表化学工业社会。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29710/'>《Polymer international》</a> <b style="margin: 0 2px;">|</b><span>2019年第11期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bal?iūnas Evaldas&option=202" target="_blank" rel="nofollow">Bal?iūnas Evaldas;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Baldock Sara J&option=202" target="_blank" rel="nofollow">Baldock Sara J;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Drei?? Nade?da&option=202" target="_blank" rel="nofollow">Drei?? Nade?da;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grubliauskait? Monika&option=202" target="_blank" rel="nofollow">Grubliauskait? Monika;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Coultas Sarah&option=202" target="_blank" rel="nofollow">Coultas Sarah;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rochester David L&option=202" target="_blank" rel="nofollow">Rochester David L;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Valius Mindaugas&option=202" target="_blank" rel="nofollow">Valius Mindaugas;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hardy John G&option=202" target="_blank" rel="nofollow">Hardy John G;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Baltriukien? Daiva&option=202" target="_blank" rel="nofollow">Baltriukien? Daiva;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Biochemistry Life Sciences CentreVilnius UniversityVilnius Lithuania;</p> <p>Department of ChemistryLancaster UniversityLancaster UK;</p> <p>Institute of Biochemistry Life Sciences CentreVilnius UniversityVilnius Lithuania;</p> <p>Institute of Biochemistry Life Sciences CentreVilnius UniversityVilnius Lithuania;</p> <p>Kratos Analytical LtdManchester UK;</p> <p>Department of ChemistryLancaster UniversityLancaster UK;</p> <p>Institute of Biochemistry Life Sciences CentreVilnius UniversityVilnius Lithuania;</p> <p>Department of ChemistryLancaster UniversityLancaster UK;</p> <p>Institute of Biochemistry Life Sciences CentreVilnius UniversityVilnius Lithuania;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1185.html" title="高分子化学（高聚物）">高分子化学（高聚物）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=3D printing&option=203" rel="nofollow">3D printing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=laser two‐photon polymerization&option=203" rel="nofollow">laser two‐photon polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photopolymers&option=203" rel="nofollow">photopolymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organometallic polymers&option=203" rel="nofollow">organometallic polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tissue engineering&option=203" rel="nofollow">tissue engineering;</a> </p> <div class="translation"> 机译：3D打印;激光双光子聚合;光聚合物;有机金属聚合物;组织工程; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024575615.html">3D printing hybrid organometallic polymer‐based biomaterials via laser two‐photon polymerization</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bal?iūnas Evaldas&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bal?iūnas Evaldas,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Baldock Sara J&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Baldock Sara J,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Drei?? 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