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Influence of alkyl methacrylate-maleic anhydride-1-hexadecene terpolymers and their mixtures with ethylene-vinyl acetate as pour point depressants in diesel fuel

机译:丙烯酸甲酯 - 马来酸酐-1-十六烯三元共聚物及其混合物与乙烯 - 乙酸乙烯酯混合物的影响,如柴油燃料中的倾点抑制剂

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摘要

In this paper, tetradecyl methacrylate-maleic anhydride-1-hexadecene (C14MC-MA-HE) terpolymers in various molar ratios was prepared and used as pour point depressants (PPDs) in 0(#) diesel fuel. Results showed that C14MC-MA-HE terpolymers exerted distinct depression effects on solid point (SP) and cold filter plugging point (CFPP) at 0.15 wt.%, especially in 4:1:1 and 4:4:1 ratio. To obtain better PPDs, the terpolymers were mixed with ethylene-vinyl acetate copolymer (EVA) at 1:1 mass ratio, and have proved to present better synergistic effects. PPDC-2 exhibited the best depression in both CFPP and SP by 20 degrees C at 0.15 wt.%. Additionally, the performance mechanism was explored.
机译:在本文中,制备各种摩尔比中的四乙基甲基丙烯酸酯 - 马来酸酐-1-十六烯(C14MC-MA-HE)三元共聚物,并用作0(#)柴油燃料中的倾点抑制剂(PPDS)。 结果表明,C14MC-MA-HE三元共聚物对固体点(SP)和冷过滤器堵塞点(CFPP)的不同抑郁效应施加0.15重量%。%,特别是在4:1:1和4:4:1的比例。 为了获得更好的PPD,将三元共聚物在1:1质量比下与乙烯 - 乙酸乙烯酯共聚物(EVA)混合,并证明了呈现更好的协同作用。 PPDC-2在0.15重量%下表现出CFPP和SP两者的最佳凹陷。%。 此外,探索了性能机制。

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