<![CDATA[Oxygen reduction reaction process of LaNi <ce:inf loc='post'>0.6</ce:inf>Fe <ce:inf loc='post'>0.4</ce:inf>O <ce:inf loc='post'>3? <ce:italic>δ</ce:italic> </ce:inf> film – porous Ce <ce:inf loc='post'>0.9</ce:inf>Gd <ce:inf loc='post'>0.1</ce:inf>O <ce:inf loc='post'>1.95</ce:inf> heterostructure electrode]]>

R.A. Budiman; S. Hashimoto; T. Nakamura; K. Yashiro; K.D. Bagarinao; H. Kishimoto; K. Yamaji; T. Horita; K. Amezawa; T. Kawada

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0.6Fe 0.4O 3? δ film – porous Ce 0.9Gd 0.1O 1.95 heterostructure electrode]]>

机译：<！[CDATA [LANI的氧气还原反应过程 0.6 FE 0.4 O <以下是什么： inf place =“post”> 3？ Δ 胶片 - 多孔孔：inf loc =“post”> 0.9 gd 0.1 O 1.95 异质结构电极]]>

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Abstract

Relevant factors affecting an oxygen reduction reaction (ORR) in a heterostructure electrode comprising a Ce0.9Gd0.1O1.95porous layer on LaNi0.6Fe0.4O3?δfilm electrode were evaluated using electrochemical impedance spectroscopy and isotope depth profile analyses. Despite the LaNi0.6Fe0.4O3?δfilm – porous Ce0.9Gd0.1O1.95electrode having higher interfacial conductivity,σE, compared to a bare LaNi0.6Fe0.4O3?δfilm electrode,σEbehavior as a function ofp(O2) was similar to each measured temperature. This exhibits a good correlation with the isotopic oxygen depth profile analysis where the evaluated surface oxygen exchange coefficient,k*, showed enhancement compared to bare LaNi0.6Fe0.4O3?δfilm and exhibited the same behavior onp(O2). Based on the analyses, there are two plausible reasons for this enhancement: (a) th

机译：<！[CDATA [什么：抽象XMLNS：什么=“http://www.elsevier.com/xml/common/dtd”xmlns =“http://www.elsevier.com/xml/ja/dtd”ID = “AB0005”XML：lang =“en”查看=“所有”类=“作者”> 抽象

影响年份氧气还原反应（ORR）在异质结构电块的相关因素组成：IM =“帖子” > 0.9 GD 0.1 O 1.95 LANI的多孔层 0.6 FE 0.4 O 3？<是什么：斜体>δ 使用电化学防止光谱和同位素深度分析析出电极。尽管LANI 0.6 FE 0.4 O 3 ？Δ 胶片 - 多孔 0.9 GD 0.1。“帖子”> e 与裸lani 0.6 FE 0.4 O 3？<是什么：斜体>δ 电极膜，斜体>Σ e 行为作为 p （o 2 ）类似于每个测量的温度。这与同位素氧气离防型材分析表现出良好的相关性，其中评估的表面氧交换系数 k *，显示增强与裸lani fe 0.4 o 3？δ < / CE：INF>薄膜并在 P （O 2 ）上表现出相同的行为。根据分析，有两种合理的原因对此增强：（a）

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来源
《Solid state ionics》 |2017年第2017期|共8页
作者
R.A. Budiman; S. Hashimoto; T. Nakamura; K. Yashiro; K.D. Bagarinao; H. Kishimoto; K. Yamaji; T. Horita; K. Amezawa; T. Kawada;
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作者单位

Graduate School of Environmental Studies Tohoku University;

Graduate School of Environmental Studies Tohoku University;

Institute of Multidisciplinary Research for Advanced Material Tohoku University;

Graduate School of Environmental Studies Tohoku University;

National Institute of Advanced Industrial Science and Technology;

National Institute of Advanced Industrial Science and Technology;

National Institute of Advanced Industrial Science and Technology;

National Institute of Advanced Industrial Science and Technology;

Institute of Multidisciplinary Research for Advanced Material Tohoku University;

Graduate School of Environmental Studies Tohoku University;

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正文语种 eng
中图分类固体物理学;
关键词
Oxygen reduction reaction; Hetero-structure; LaNi0.6Fe0.4O3?δ; Ce0.9Gd0.1O1.95;

机译：氧还原反应;杂结构;LANI0.6FE0.4O3？δ;CE0.9GD0.1O1.95;

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0.6Fe 0.4O 3? δ film – porous Ce 0.9Gd 0.1O 1.95 heterostructure electrode]]>

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