Fabrication of MnO 2/TiO 2 nano-tube arrays photoelectrode and its enhanced visible light photoelectrocatalytic performance and mechanism

摘要

Graphical abstractDisplay OmittedHighlights?MnO2/TiO2NTAs was fabricated by electrodeposition process.?MnO2/TiO2NTAs exhibited superior physicochemical properties.?Effect of fabricating parameters on PC degradation of pollutants was studied.?The enhanced visible PEC mechanism of MnO2/TiO2NTAs was proposed.AbstractMnO2/TiO2nano-tube arrays (MnO2/TiO2NTAs) photoelectrode was synthesized through anodization and electrodeposition, followed by the prepared conditions optimized. Subsequently, structures of the as-prepared photoelectrodes were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Besides, the light absorption capacities and photoelectrochemical (PECH) properties were investigated through UV–vis diffuse reflectance spectrophotometer (UV–vis DRS), photocurrent response (PCR) and electrochemical impedance spectroscopy (EIS). In addition, these photoelectrodes were used for the photoelectrocatalytic (PEC) degradation of methylene orange (MO) under Xenon lamp irradiation. Moreover, the enhanced PEC mechanism was further confirmed through scavengering effect and photoluminsecence (PL) spectra. Results presented that the highly ordered TiO2nano-tube arrays photoelectrodes processed a uniform sizes of inner diameter of 300nm and well thickness of 60nm with MnO2nanoparticles successfully deposited. Furthermore, it was found that these novel MnO2/TiO2NTAs photoelectrodes could not only red-shift the light absorption to visible region between 400nm and 700nm, but also significantly enhance the generation of hydroxyl radicals (OH) which played an important role in the PEC system. Noticeably, the MnO2/TiO2NTAs photoelectrodes made in the optimized conditions exhibited much higher PEC activity toward MO degradation with the efficiency up to 95.2% within 1h when external potential (+2.0V) was applied. More importantly, these novel MnO2/TiO2NTAs photoelectrodes proved to have excellent stability and reusability that would have great potentials for organic contaminants degradation in wastewater treatment.]]