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A study of the intermolecular interactions of lipid components from analogue fingerprint residues

机译:模拟指纹残基脂质成分分子间相互作用的研究

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摘要

A compositionally simplified analogue of a latent fingermark was created by combining single representatives of each major component of a natural fingermark. Further modified analogues were also produced each having one component removed. The aim of this study was to investigate the intermolecular interactions that occurred within these analogue samples using Fourier Transform Infrared (FT-IR) Microspectroscopy. FT-IR micro spectroscopy showed that the absence of squalene and cholesterol significantly restricted the interactions between the other organic constituents within the analogue samples. Investigating the intermolecular interactions of organic compounds within a simplified analogue solution could indicate corresponding interactions that occur within natural fingermarks. These potential interactions could go on to be the target of further investigation of latent fingermark chemistry, and ultimately contribute to a better understanding of the aging processes and degradation mechanisms that take place post-deposition.
机译:通过组合自然Fingermark的每个主要组分的单个代表来产生潜伏的Fingermark的组成简化类似物。还产生了另外的改性类似物,每个组分除去一个组分。本研究的目的是使用傅里叶变换红外(FT-IR)微型光谱检查来研究这些模拟样品内发生的分子间相互作用。 FT-IR微光谱表明,不存在角鲨烯和胆固醇显着地限制了类似物样品内的其他有机成分之间的相互作用。研究简化的类似物溶液内有机化合物的分子间相互作用可以指示天然指状物内发生的相应相互作用。这些潜在的相互作用可以继续进一步调查潜在的Fingermark化学的目标,并最终有助于更好地理解沉积后发生的老化过程和降解机制。

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